Publikation: Localization and bandwidth of the 3d-orbitals in magnetic Ni and Co clusters
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2000
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Pure and Applied Chemistry. 2000, 72(11), pp. 2149-2157. Available under: doi: 10.1351/pac200072112149
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Photoelectron spectra of negatively charged Nin- , Cun-, and Con- clusters are presented. The spectra of the Nin- clusters contain information about the degree of localization of the 3d valence orbitals, which is strongly related to the magnetic properties. In the clusters with less than 7 atoms, the 3d orbitals seem to be almost totally localized. For Co13- we find indications of a narrowing of the 3d-derived valence "bandwidth" corresponding to a presumed high symmetry and a high degree of degeneracy of the 3d electronic states.
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MORENZIN, Jan, Hardy KIETZMANN, Paul S. BECHTHOLD, Gerd GANTEFÖR, Wolfgang EBERHARDT, 2000. Localization and bandwidth of the 3d-orbitals in magnetic Ni and Co clusters. In: Pure and Applied Chemistry. 2000, 72(11), pp. 2149-2157. Available under: doi: 10.1351/pac200072112149BibTex
@article{Morenzin2000Local-9127, year={2000}, doi={10.1351/pac200072112149}, title={Localization and bandwidth of the 3d-orbitals in magnetic Ni and Co clusters}, number={11}, volume={72}, journal={Pure and Applied Chemistry}, pages={2149--2157}, author={Morenzin, Jan and Kietzmann, Hardy and Bechthold, Paul S. and Ganteför, Gerd and Eberhardt, Wolfgang} }
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