Publikation:

Localization and bandwidth of the 3d-orbitals in magnetic Ni and Co clusters

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PureAppChem722000.pdf
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2000

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Morenzin, Jan
Kietzmann, Hardy
Bechthold, Paul S.
Eberhardt, Wolfgang

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http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-87260
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https://doi.org/10.1351/pac200072112149
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Pure and Applied Chemistry. 2000, 72(11), pp. 2149-2157. Available under: doi: 10.1351/pac200072112149

Zusammenfassung

Photoelectron spectra of negatively charged Nin- , Cun-, and Con- clusters are presented. The spectra of the Nin- clusters contain information about the degree of localization of the 3d valence orbitals, which is strongly related to the magnetic properties. In the clusters with less than 7 atoms, the 3d orbitals seem to be almost totally localized. For Co13- we find indications of a narrowing of the 3d-derived valence "bandwidth" corresponding to a presumed high symmetry and a high degree of degeneracy of the 3d electronic states.

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ISO 690MORENZIN, Jan, Hardy KIETZMANN, Paul S. BECHTHOLD, Gerd GANTEFÖR, Wolfgang EBERHARDT, 2000. Localization and bandwidth of the 3d-orbitals in magnetic Ni and Co clusters. In: Pure and Applied Chemistry. 2000, 72(11), pp. 2149-2157. Available under: doi: 10.1351/pac200072112149
BibTex
@article{Morenzin2000Local-9127,
  year={2000},
  doi={10.1351/pac200072112149},
  title={Localization and bandwidth of the 3d-orbitals in magnetic Ni and Co clusters},
  number={11},
  volume={72},
  journal={Pure and Applied Chemistry},
  pages={2149--2157},
  author={Morenzin, Jan and Kietzmann, Hardy and Bechthold, Paul S. and Ganteför, Gerd and Eberhardt, Wolfgang}
}
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