Publikation:

Oxidative Perhydroxylation of [closo-B12H12]2- ; to the Stable Inorganic Cluster Redox System [B12(OH)12]2-/.- : Experiment and Theory

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Schleid_Winter_CEJ_2010.pdf
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2010

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Van, Nguyen
Tiritiris, Ioannis
Sarkar, Biprajit
Singh, Priti
Duboc, Carole
Muñoz-Castro, Alvaro
Arratia-Pérez, Ramiro
Kaim, Wolfgang
Schleid, Thomas

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http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-129034
DOI (zitierfähiger Link)
https://doi.org/10.1002/chem.201001374
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Chemie: Publikationen
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Published

Erschienen in

Chemistry: a European Journal. 2010, 16(37), pp. 11242-11245. eISSN 0947-6539. Available under: doi: 10.1002/chem.201001374

Zusammenfassung

It′s radical: A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster [closo-B12H12]2− not only to [closo-B12(OH)12]2− but also, at less-elevated temperatures, to the new [hypocloso-B12(OH)12].− radical anion (see figure). Both approximately icosahedral closo and hypocloso cluster ions were structurally characterized as the cesium salts and their properties were assessed experimentally and theoretically.

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Fachgebiet (DDC)
540 Chemie

Schlagwörter

borates, cage compounds, closomers, electron-deficient compounds, hydroxylation, radicals

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ISO 690VAN, Nguyen, Ioannis TIRITIRIS, Rainer F. WINTER, Biprajit SARKAR, Priti SINGH, Carole DUBOC, Alvaro MUÑOZ-CASTRO, Ramiro ARRATIA-PÉREZ, Wolfgang KAIM, Thomas SCHLEID, 2010. Oxidative Perhydroxylation of [closo-B12H12]2- ; to the Stable Inorganic Cluster Redox System [B12(OH)12]2-/.- : Experiment and Theory. In: Chemistry: a European Journal. 2010, 16(37), pp. 11242-11245. eISSN 0947-6539. Available under: doi: 10.1002/chem.201001374
BibTex
@article{Van2010Oxida-9599,
  year={2010},
  doi={10.1002/chem.201001374},
  title={Oxidative Perhydroxylation of [<em>closo</em>-B<sub>12</sub>H<sub>12</sub>]<sup>2-</sup> ; to the Stable Inorganic Cluster Redox System [B<sub>12</sub>(OH)<sub>12</sub>]<sup>2-/.-</sup> : Experiment and Theory},
  number={37},
  volume={16},
  journal={Chemistry: a European Journal},
  pages={11242--11245},
  author={Van, Nguyen and Tiritiris, Ioannis and Winter, Rainer F. and Sarkar, Biprajit and Singh, Priti and Duboc, Carole and Muñoz-Castro, Alvaro and Arratia-Pérez, Ramiro and Kaim, Wolfgang and Schleid, Thomas}
}
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    <dcterms:abstract xml:lang="eng">&lt;b&gt;It&amp;#8242;s radical&lt;/b&gt;: A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster [&lt;em&gt;closo&lt;/em&gt;-B&lt;sub&gt;12&lt;/sub&gt;H&lt;sub&gt;12&lt;/sub&gt;]&lt;sup&gt;2&amp;#8722;&lt;/sup&gt; not only to [&lt;em&gt;closo&lt;/em&gt;-B&lt;sub&gt;12&lt;/sub&gt;(OH)&lt;sub&gt;12&lt;/sub&gt;]&lt;sup&gt;2&amp;#8722;&lt;/sup&gt; but also, at less-elevated temperatures, to the new [&lt;em&gt;hypocloso&lt;/em&gt;-B&lt;sub&gt;12&lt;/sub&gt;(OH)&lt;sub&gt;12&lt;/sub&gt;]&lt;sup&gt;.&amp;#8722;&lt;/sup&gt; radical anion (see figure). Both approximately icosahedral &lt;em&gt;closo&lt;/em&gt; and &lt;em&gt;hypocloso&lt;/em&gt; cluster ions were structurally characterized as the cesium salts and their properties were assessed experimentally and theoretically.</dcterms:abstract>
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