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Cyclopenta[l]phenanthrene titanium trichloride derivatives : syntheses, crystal structure and properties as catalysts for styrene polymerization

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Schneider_238893.pdf
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1997

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Schneider, Nicole
Prosenc, Marc-Heinrich

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Journal of Organometallic Chemistry. 1997, 545-546, pp. 291-295. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(97)00251-9

Zusammenfassung

Cyclopenta[l]phenanthrene titanium trichloride and its 2-methyl and phenyl derivatives were synthesized; the crystal structure of the 2-methyl-substituted complex was determined by X-ray diffraction analysis. In the presence of methylalurnoxane (MAO), these complexes give highly active catalysis for the syndiotactic polymerization of styrene; the 2-phenyl-substituted complex exceeds all previously described catalysis in its catalytic activity.

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540 Chemie

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ISO 690SCHNEIDER, Nicole, Marc-Heinrich PROSENC, Hans-Herbert BRINTZINGER, 1997. Cyclopenta[l]phenanthrene titanium trichloride derivatives : syntheses, crystal structure and properties as catalysts for styrene polymerization. In: Journal of Organometallic Chemistry. 1997, 545-546, pp. 291-295. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(97)00251-9
BibTex
@article{Schneider1997Cyclo-23889,
  year={1997},
  doi={10.1016/S0022-328X(97)00251-9},
  title={Cyclopenta[l]phenanthrene titanium trichloride derivatives : syntheses, crystal structure and properties as catalysts for styrene polymerization},
  volume={545-546},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={291--295},
  author={Schneider, Nicole and Prosenc, Marc-Heinrich and Brintzinger, Hans-Herbert}
}
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