Publikation: Cyclopenta[l]phenanthrene titanium trichloride derivatives : syntheses, crystal structure and properties as catalysts for styrene polymerization
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1997
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Journal of Organometallic Chemistry. 1997, 545-546, pp. 291-295. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(97)00251-9
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Cyclopenta[l]phenanthrene titanium trichloride and its 2-methyl and phenyl derivatives were synthesized; the crystal structure of the 2-methyl-substituted complex was determined by X-ray diffraction analysis. In the presence of methylalurnoxane (MAO), these complexes give highly active catalysis for the syndiotactic polymerization of styrene; the 2-phenyl-substituted complex exceeds all previously described catalysis in its catalytic activity.
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SCHNEIDER, Nicole, Marc-Heinrich PROSENC, Hans-Herbert BRINTZINGER, 1997. Cyclopenta[l]phenanthrene titanium trichloride derivatives : syntheses, crystal structure and properties as catalysts for styrene polymerization. In: Journal of Organometallic Chemistry. 1997, 545-546, pp. 291-295. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(97)00251-9BibTex
@article{Schneider1997Cyclo-23889,
year={1997},
doi={10.1016/S0022-328X(97)00251-9},
title={Cyclopenta[l]phenanthrene titanium trichloride derivatives : syntheses, crystal structure and properties as catalysts for styrene polymerization},
volume={545-546},
issn={0022-328X},
journal={Journal of Organometallic Chemistry},
pages={291--295},
author={Schneider, Nicole and Prosenc, Marc-Heinrich and Brintzinger, Hans-Herbert}
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