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Synthesis of a Large Organometallic Macrocycle Comprising Four Ga−Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands

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Uhl_Synthesis.pdf
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2000

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Uhl, Werner
Spies, Thomas
Haase, Detlev
Kaim, Wolfgang

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Organometallics. 2000, 19(6), pp. 1128-1131. ISSN 0276-7333. Available under: doi: 10.1021/om990875q

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The reaction of tetrakis[bis(trimethylsilyl)methyl]digallane(4), 1, with 1,1‘-ferrocenedicarboxylic acid afforded orange-red crystals of the macrocyclic compound 2 in a yield of 84%. 2 contains a large 32-atom heterocycle, which comprises four Ga−Ga single bonds bridged by four 1,1‘-ferrocenedicarboxylato ligands. The largest diameter of the molecule is about 2.5 nm. The redox-active Ga−Ga sites and ferrocene iron centers are all oxidized irreversibly within a narrow potential range.

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ISO 690UHL, Werner, Thomas SPIES, Detlev HAASE, Rainer F. WINTER, Wolfgang KAIM, 2000. Synthesis of a Large Organometallic Macrocycle Comprising Four Ga−Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands. In: Organometallics. 2000, 19(6), pp. 1128-1131. ISSN 0276-7333. Available under: doi: 10.1021/om990875q
BibTex
@article{Uhl2000Synth-13818,
  year={2000},
  doi={10.1021/om990875q},
  title={Synthesis of a Large Organometallic Macrocycle Comprising Four Ga−Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands},
  number={6},
  volume={19},
  issn={0276-7333},
  journal={Organometallics},
  pages={1128--1131},
  author={Uhl, Werner and Spies, Thomas and Haase, Detlev and Winter, Rainer F. and Kaim, Wolfgang}
}
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