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Size Control of Spherical and Anisotropic Fluorescent Polymer Nanoparticles via Precise Rigid Molecules

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2015

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https://doi.org/10.1021/acs.macromol.5b00591
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Macromolecules. 2015, 48(12), pp. 3900-3906. ISSN 0024-9297. eISSN 1520-5835. Available under: doi: 10.1021/acs.macromol.5b00591

Zusammenfassung

Highly monodisperse block copolymers allow for the preparation of luminescent particles with sizes reflecting the oligomer chain length. Self-organization in tetrahydrofuran/methanol leads to anisotropic nanorods with a thickness corresponding directly to the oligomer length (up to 14 nm for 21-mers). As a prerequisite for the realization of this concept, syntheses of defect-free poly(phenylene ethynylene)s with unprecedented chain length up to 43 repeat units were developed. Absorption and emission wavelength in solution continue to increase with increasing chain length, and do not converge until the 43-mer.

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ISO 690SCHÜTZE, Friederike, Marina KRUMOVA, Stefan MECKING, 2015. Size Control of Spherical and Anisotropic Fluorescent Polymer Nanoparticles via Precise Rigid Molecules. In: Macromolecules. 2015, 48(12), pp. 3900-3906. ISSN 0024-9297. eISSN 1520-5835. Available under: doi: 10.1021/acs.macromol.5b00591
BibTex
@article{Schutze2015Contr-31417,
  year={2015},
  doi={10.1021/acs.macromol.5b00591},
  title={Size Control of Spherical and Anisotropic Fluorescent Polymer Nanoparticles via Precise Rigid Molecules},
  number={12},
  volume={48},
  issn={0024-9297},
  journal={Macromolecules},
  pages={3900--3906},
  author={Schütze, Friederike and Krumova, Marina and Mecking, Stefan}
}
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