@article{Baur2022-10-18Polye-58927,
  year={2022},
  doi={10.1021/acsmacrolett.2c00459},
  title={Polyethylenes with Combined In-Chain and Side-Chain Functional Groups from Catalytic Terpolymerization of Carbon Monoxide and Acrylate},
  number={10},
  volume={11},
  journal={ACS Macro Letters},
  pages={1207--1211},
  author={Baur, Maximilian and Mecking, Stefan}
}

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    <dcterms:title>Polyethylenes with Combined In-Chain and Side-Chain Functional Groups from Catalytic Terpolymerization of Carbon Monoxide and Acrylate</dcterms:title>
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    <dc:creator>Mecking, Stefan</dc:creator>
    <dc:contributor>Baur, Maximilian</dc:contributor>
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    <dcterms:abstract xml:lang="eng">Linear polyethylenes with a combination of incorporated in-chain keto as well as side-chain ester groups are formed by Ni(II)-catalyzed terpolymerization of ethylene, carbon monoxide, and methyl acrylate. These possess a random structure, with largely isolated nonalternating in-chain keto groups as well as ester-substituted units adjacent to the polyethylene chain, whereas the solid-state structure of polyethylene is retained. Molecular weights of the terpolymers (M&lt;sub&gt;n&lt;/sub&gt; ∼ 20.000 g mol&lt;sup&gt;–1&lt;/sup&gt;) are predominantly determined by chain transfer after acrylate incorporation.</dcterms:abstract>
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    <dc:contributor>Mecking, Stefan</dc:contributor>
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