Realization of high performance flexible wire supercapacitors based on 3-dimensional NiCo2O4/Ni fibers

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2016
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Kang, Kyeong-Nam
Ahn, Hyo-Jin
Kim, Sun-I
Ryu, Seung-Tak
Jang, Ji-Hyun
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Journal of Materials Chemistry A. 2016, 4(13), pp. 4718-4727. ISSN 2050-7488. eISSN 2050-7496. Available under: doi: 10.1039/C5TA10781D
Zusammenfassung

The rapidly developing electronics industry is producing miniaturized electronic devices with flexible, portable and wearable characteristics, requiring high-performance miniature energy storage devices with flexible and light weight properties. Herein, we have successfully fabricated highly porous, binder free three-dimensional flower-like NiCo2O4/Ni nanostructures on Ni-wire as a fiber electrode for high-performance flexible fiber supercapacitors. Such a unique structure exhibited remarkable electrochemical performance with high capacitance (29.7 F cm−3 at 2.5 mA), excellent rate capability (97.5% retention at 20 mA), and super cycling stability (80% retention, even after 5000 cycles). The remarkable electrochemical performance is attributed to the large active area in the 3D porous architecture and direct contact between the active materials and 3D-Ni current collectors, which facilitate easy ionic/electronic transport. The symmetric fiber supercapacitor showed a gravimetric energy density of 2.18 W h kg−1 (0.21 mW h cm−3) and a power density of 21.6 W kg−1 (2.1 mW cm−3) with good flexibility and cycling performance, signifying potential applications in high-performance flexible energy storage devices. Further, performance in a self-powered system was demonstrated by charging these wire type NiCo2O4/Ni supercapacitors by serially wound DSSCs to drive commercial LEDs. These results suggest that the fabricated device has excellent potential as a power source for flexible, portable and wearable applications as well as self-powered systems.

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ISO 690RAMADOSS, Ananthakumar, Kyeong-Nam KANG, Hyo-Jin AHN, Sun-I KIM, Seung-Tak RYU, Ji-Hyun JANG, 2016. Realization of high performance flexible wire supercapacitors based on 3-dimensional NiCo2O4/Ni fibers. In: Journal of Materials Chemistry A. 2016, 4(13), pp. 4718-4727. ISSN 2050-7488. eISSN 2050-7496. Available under: doi: 10.1039/C5TA10781D
BibTex
@article{Ramadoss2016Reali-37040,
  year={2016},
  doi={10.1039/C5TA10781D},
  title={Realization of high performance flexible wire supercapacitors based on 3-dimensional NiCo<sub>2</sub>O<sub>4</sub>/Ni fibers},
  number={13},
  volume={4},
  issn={2050-7488},
  journal={Journal of Materials Chemistry A},
  pages={4718--4727},
  author={Ramadoss, Ananthakumar and Kang, Kyeong-Nam and Ahn, Hyo-Jin and Kim, Sun-I and Ryu, Seung-Tak and Jang, Ji-Hyun}
}
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