Publikation: Metal-Free Electrochemical Allylic C–H Aerobic Oxidation
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2025
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National Natural Science Foundation of China: 22371129
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The Journal of Organic Chemistry. ACS Publications. 2025, 90(2), S. 1148-1158. ISSN 0022-3263. eISSN 1520-6904. Verfügbar unter: doi: 10.1021/acs.joc.4c02793
Zusammenfassung
A scalable and sustainable electrochemical protocol for allylic C–H aerobic oxidation has been developed, enabling the formation of enones without the use of stoichiometric toxic oxidants or metal catalysts and offering an environmentally benign alternative to traditional chemical oxidation techniques. The process has been successfully applied to selectively oxidize a series of natural products and drug molecules, underscoring its potential for widespread adoption in both academic and industrial contexts.
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540 Chemie
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SHEN, Tong, Jianyou ZHAO, Xuanxuan REN, Zhong-Quan LIU, Shuai LIU, 2025. Metal-Free Electrochemical Allylic C–H Aerobic Oxidation. In: The Journal of Organic Chemistry. ACS Publications. 2025, 90(2), S. 1148-1158. ISSN 0022-3263. eISSN 1520-6904. Verfügbar unter: doi: 10.1021/acs.joc.4c02793BibTex
@article{Shen2025-01-08Metal-71979, title={Metal-Free Electrochemical Allylic C–H Aerobic Oxidation}, year={2025}, doi={10.1021/acs.joc.4c02793}, number={2}, volume={90}, issn={0022-3263}, journal={The Journal of Organic Chemistry}, pages={1148--1158}, author={Shen, Tong and Zhao, Jianyou and Ren, Xuanxuan and Liu, Zhong-Quan and Liu, Shuai} }
RDF
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