Publikation: Dicyclopentadienyltitanium(IV) pyridine-2,6-dicarboxylate complexes : Synthesis and structural characterization as pentacoordinate titanocene derivatives
Lade...
Dateien
Datum
1986
Autor:innen
Herausgeber:innen
ISSN der Zeitschrift
Electronic ISSN
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
URI (zitierfähiger Link)
DOI (zitierfähiger Link)
Internationale Patentnummer
Link zur Lizenz
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Open Access Green
Sammlungen
Core Facility der Universität Konstanz
Titel in einer weiteren Sprache
Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published
Erschienen in
Journal of Organometallic Chemistry. 1986, 312(2), pp. 177-182. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(86)80296-0
Zusammenfassung
Reaction of (C5H5)2Ti(CH3)2 or (CH3)4C2(C5H4)2Ti(CH3)2 with pyridine-2,6-dicarboxylic acid (dipicolinic acid) yields titanocene dipicolinate derivatives. The molecular structure of (C5H5)2Ti dipicolinate is that of an axially symmetric, pentacoordinate titanocene derivative with two carboxyl oxygen atoms and the pyridine nitrogen atom as ligating atoms. Two identical chelate bite angles of only 71° make the dipicolinate ligand particularly suited to form a remarkably stable titanocene derivative with unprecedented pentacoordintae geometry.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
540 Chemie
Schlagwörter
Konferenz
Rezension
undefined / . - undefined, undefined
Zitieren
ISO 690
LEIK, Regina, Laszlo ZSOLNAI, Gottfried HUTTNER, Eberhard W. NEUSE, Hans-Herbert BRINTZINGER, 1986. Dicyclopentadienyltitanium(IV) pyridine-2,6-dicarboxylate complexes : Synthesis and structural characterization as pentacoordinate titanocene derivatives. In: Journal of Organometallic Chemistry. 1986, 312(2), pp. 177-182. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(86)80296-0BibTex
@article{Leik1986Dicyc-23985, year={1986}, doi={10.1016/0022-328X(86)80296-0}, title={Dicyclopentadienyltitanium(IV) pyridine-2,6-dicarboxylate complexes : Synthesis and structural characterization as pentacoordinate titanocene derivatives}, number={2}, volume={312}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={177--182}, author={Leik, Regina and Zsolnai, Laszlo and Huttner, Gottfried and Neuse, Eberhard W. and Brintzinger, Hans-Herbert} }
RDF
<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/23985"> <dc:contributor>Brintzinger, Hans-Herbert</dc:contributor> <dcterms:abstract xml:lang="eng">Reaction of (C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>Ti(CH<sub>3</sub>)<sub>2</sub> or (CH<sub>3</sub>)<sub>4</sub>C<sub>2</sub>(C<sub>5</sub>H<sub>4</sub>)<sub>2</sub>Ti(CH<sub>3</sub>)<sub>2</sub> with pyridine-2,6-dicarboxylic acid (dipicolinic acid) yields titanocene dipicolinate derivatives. The molecular structure of (C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>Ti dipicolinate is that of an axially symmetric, pentacoordinate titanocene derivative with two carboxyl oxygen atoms and the pyridine nitrogen atom as ligating atoms. Two identical chelate bite angles of only 71° make the dipicolinate ligand particularly suited to form a remarkably stable titanocene derivative with unprecedented pentacoordintae geometry.</dcterms:abstract> <dc:creator>Brintzinger, Hans-Herbert</dc:creator> <foaf:homepage rdf:resource="http://localhost:8080/"/> <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/> <dc:contributor>Zsolnai, Laszlo</dc:contributor> <dcterms:title>Dicyclopentadienyltitanium(IV) pyridine-2,6-dicarboxylate complexes : Synthesis and structural characterization as pentacoordinate titanocene derivatives</dcterms:title> <dc:creator>Huttner, Gottfried</dc:creator> <dc:rights>terms-of-use</dc:rights> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-07-10T09:36:32Z</dc:date> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/23985"/> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/23985/1/Leik_239859.pdf"/> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/23985/1/Leik_239859.pdf"/> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/> <dc:creator>Neuse, Eberhard W.</dc:creator> <dc:language>eng</dc:language> <dc:creator>Leik, Regina</dc:creator> <dcterms:bibliographicCitation>Journal of Organometallic Chemistry ; 312 (1986), 2. - S. 177-182</dcterms:bibliographicCitation> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/> <dc:contributor>Huttner, Gottfried</dc:contributor> <dcterms:issued>1986</dcterms:issued> <dc:creator>Zsolnai, Laszlo</dc:creator> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-07-10T09:36:32Z</dcterms:available> <dc:contributor>Neuse, Eberhard W.</dc:contributor> <dc:contributor>Leik, Regina</dc:contributor> </rdf:Description> </rdf:RDF>