Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

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2019
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Magnabosco, Giulia
Condorelli, Andrea M. M.
Polishchuk, Iryna
Pokroy, Boaz
Falini, Giuseppe
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Chemical Communications. 2019, 55(86), pp. 12944-12947. ISSN 0009-241X. eISSN 1364-548X. Available under: doi: 10.1039/C9CC07087G
Zusammenfassung

The effect of Mg2+ on the precipitation pathway of CaCO3 in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg2+ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.

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ISO 690MAGNABOSCO, Giulia, Andrea M. M. CONDORELLI, Rose ROSENBERG, Iryna POLISHCHUK, Boaz POKROY, Denis GEBAUER, Helmut CÖLFEN, Giuseppe FALINI, 2019. Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol. In: Chemical Communications. 2019, 55(86), pp. 12944-12947. ISSN 0009-241X. eISSN 1364-548X. Available under: doi: 10.1039/C9CC07087G
BibTex
@article{Magnabosco2019-10-24Nonst-47193,
  year={2019},
  doi={10.1039/C9CC07087G},
  title={Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol},
  number={86},
  volume={55},
  issn={0009-241X},
  journal={Chemical Communications},
  pages={12944--12947},
  author={Magnabosco, Giulia and Condorelli, Andrea M. M. and Rosenberg, Rose and Polishchuk, Iryna and Pokroy, Boaz and Gebauer, Denis and Cölfen, Helmut and Falini, Giuseppe}
}
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