Publikation:

Metallo‐Scorpionates : First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu)

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2018

Autor:innen

Schlapp-Hackl, Inge
Wurst, Klaus
Kopacka, Holger
Müller, Thomas
Bildstein, Benno

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http://nbn-resolving.de/urn:nbn:de:bsz:352-2-1mu0ksg88l89c6
DOI (zitierfähiger Link)
https://doi.org/10.1002/ejic.201800774
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CC BY-NC-ND 4.0

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Chemie: Publikationen
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Published

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European Journal of Inorganic Chemistry. 2018, 2018(40), pp. 4434-4441. ISSN 1434-1948. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201800774

Zusammenfassung

The first metallo‐scorpionate ligands, closely related to Trofimenko's scorpionates, are obtained by formal replacement of the hydrido‐boron moiety of hydrido‐tris(pyrazolyl)borate by an (arene)RuII fragment. Coordination to divalent and trivalent 3d‐transition metals (Fe, Co, Ni, Cu) gives access to a series of homoleptic, heterotrimetallic complexes containing linear metal chains bridged by pyrazole ligands. Synthetic aspects, spectroscopic, structural and electrochemical properties are reported and compared to those of standard scorpionate complexes.

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540 Chemie

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ISO 690SCHLAPP-HACKL, Inge, Christopher HASSENRÜCK, Klaus WURST, Holger KOPACKA, Thomas MÜLLER, Rainer F. WINTER, Benno BILDSTEIN, 2018. Metallo‐Scorpionates : First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu). In: European Journal of Inorganic Chemistry. 2018, 2018(40), pp. 4434-4441. ISSN 1434-1948. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201800774
BibTex
@article{SchlappHackl2018-11-01Metal-44250,
  year={2018},
  doi={10.1002/ejic.201800774},
  title={Metallo‐Scorpionates : First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu)},
  number={40},
  volume={2018},
  issn={1434-1948},
  journal={European Journal of Inorganic Chemistry},
  pages={4434--4441},
  author={Schlapp-Hackl, Inge and Hassenrück, Christopher and Wurst, Klaus and Kopacka, Holger and Müller, Thomas and Winter, Rainer F. and Bildstein, Benno}
}
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