Publikation: ansa-metallocene derivatives XXXIX biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium : syntheses, crystal structures and enantioseparation
Dateien
Datum
Autor:innen
Herausgeber:innen
ISSN der Zeitschrift
Electronic ISSN
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
URI (zitierfähiger Link)
DOI (zitierfähiger Link)
Internationale Patentnummer
Link zur Lizenz
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Sammlungen
Core Facility der Universität Konstanz
Titel in einer weiteren Sprache
Publikationstyp
Publikationsstatus
Erschienen in
Zusammenfassung
Chiral, biphenyl-bridged metallocene complexes of general type biph(3,4-R2C5H2)2MCl2 (biph = 1,1'-biphenyldiyl) were synthesized and characterized. For the dimethyl-substituted titanocenes and zirconocenes (R = CH3; M = Ti, Zr), preparations with increased overall yields and an optical resolution method were developed. The bis(2-tetrahydroindenyl) complexes (R,R = (CH2)4; M = Ti, Zr) were obtained by an alternative synthetic route and characterized with regard to their crystal structures. Syntheses of the phenyl-substituted derivatives (R = C6H5; M = Ti, Zr) and of a chiral, methyl-substituted vanadocene complex (R = CH3; M = V) are also reported.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
Schlagwörter
Konferenz
Rezension
Zitieren
ISO 690
HUTTENLOCH, Monika E., Birgit DORER, Ursula RIEF, Marc-Heinrich PROSENC, Katrin SCHMIDT, Hans-Herbert BRINTZINGER, 1997. ansa-metallocene derivatives XXXIX biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium : syntheses, crystal structures and enantioseparation. In: Journal of Organometallic Chemistry. 1997, 541(1-2), pp. 219-232. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(97)00064-8BibTex
@article{Huttenloch1997ansam-23890, year={1997}, doi={10.1016/S0022-328X(97)00064-8}, title={ansa-metallocene derivatives XXXIX biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium : syntheses, crystal structures and enantioseparation}, number={1-2}, volume={541}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={219--232}, author={Huttenloch, Monika E. and Dorer, Birgit and Rief, Ursula and Prosenc, Marc-Heinrich and Schmidt, Katrin and Brintzinger, Hans-Herbert} }
RDF
<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/23890"> <dcterms:bibliographicCitation>Journal of Organometallic Chemistry ; 541 (1997), 1-2. - S. 219-232</dcterms:bibliographicCitation> <dcterms:abstract xml:lang="eng">Chiral, biphenyl-bridged metallocene complexes of general type biph(3,4-R<sub>2</sub>C<sub>5</sub>H<sub>2</sub>)<sub>2</sub>MCl<sub>2</sub> (biph = 1,1'-biphenyldiyl) were synthesized and characterized. For the dimethyl-substituted titanocenes and zirconocenes (R = CH<sub>3</sub>; M = Ti, Zr), preparations with increased overall yields and an optical resolution method were developed. The bis(2-tetrahydroindenyl) complexes (R,R = (CH<sub>2</sub>)4; M = Ti, Zr) were obtained by an alternative synthetic route and characterized with regard to their crystal structures. Syntheses of the phenyl-substituted derivatives (R = C<sub>6</sub>H<sub>5</sub>; M = Ti, Zr) and of a chiral, methyl-substituted vanadocene complex (R = CH<sub>3</sub>; M = V) are also reported.</dcterms:abstract> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-07-25T08:36:18Z</dc:date> <dc:contributor>Prosenc, Marc-Heinrich</dc:contributor> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/23890/1/Huttenloch_238908.pdf"/> <dc:rights>terms-of-use</dc:rights> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/23890/1/Huttenloch_238908.pdf"/> <dc:creator>Rief, Ursula</dc:creator> <dc:creator>Brintzinger, Hans-Herbert</dc:creator> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:contributor>Brintzinger, Hans-Herbert</dc:contributor> <foaf:homepage rdf:resource="http://localhost:8080/"/> <dc:creator>Huttenloch, Monika E.</dc:creator> <dc:creator>Schmidt, Katrin</dc:creator> <dc:contributor>Rief, Ursula</dc:contributor> <dcterms:issued>1997</dcterms:issued> <dc:creator>Prosenc, Marc-Heinrich</dc:creator> <dc:contributor>Schmidt, Katrin</dc:contributor> <dc:creator>Dorer, Birgit</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/23890"/> <dcterms:title>ansa-metallocene derivatives XXXIX biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium : syntheses, crystal structures and enantioseparation</dcterms:title> <dc:contributor>Huttenloch, Monika E.</dc:contributor> <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-07-25T08:36:18Z</dcterms:available> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/> <dc:contributor>Dorer, Birgit</dc:contributor> <dc:language>eng</dc:language> </rdf:Description> </rdf:RDF>