Low oxidation state aluminum-containing cluster anions: Cp∗AlnH−, n = 1–3

Kurzanzeige
dc.contributor.authorZhang, Xinxing
dc.contributor.authorGanteför, Gerd
dc.contributor.authorEichhorn, Bryan
dc.contributor.authorMayo, Dennis
dc.contributor.authorSawyer, William H
dc.contributor.authorGill, Ann F
dc.contributor.authorKandalam, Anil K.
dc.contributor.authorSchnöckel, Hansgeorg
dc.contributor.authorBowen, Kit
dc.date.accessioned2017-01-25T10:50:01Z
dc.date.available2017-01-25T10:50:01Z
dc.date.issued2016eng
dc.description.abstractThree new, low oxidation state, aluminum-containing cluster anions, Cp*AlnH(-), n = 1-3, were prepared via reactions between aluminum hydride cluster anions, AlnHm (-), and Cp*H ligands. These were characterized by mass spectrometry, anion photoelectron spectroscopy, and density functional theory based calculations. Agreement between the experimentally and theoretically determined vertical detachment energies and adiabatic detachment energies validated the computed geometrical structures. Reactions between aluminum hydride cluster anions and ligands provide a new avenue for discovering low oxidation state, ligated aluminum clusters.eng
dc.description.versionpublishedeng
dc.identifier.doi10.1063/1.4959847eng
dc.identifier.pmid27544103eng
dc.identifier.urihttps://kops.uni-konstanz.de/handle/123456789/36947
dc.language.isoengeng
dc.subject.ddc530eng
dc.titleLow oxidation state aluminum-containing cluster anions: Cp<sup>∗</sup>Al<sub>n</sub>H<sup>−</sup>, n = 1–3eng
dc.typeJOURNAL_ARTICLEeng
dspace.entity.typePublication
kops.citation.bibtex
@article{Zhang2016oxida-36947,
  year={2016},
  doi={10.1063/1.4959847},
  title={Low oxidation state aluminum-containing cluster anions: Cp<sup>∗</sup>Al<sub>n</sub>H<sup>−</sup>, n = 1–3},
  number={7},
  volume={145},
  issn={0021-9606},
  journal={The Journal of Chemical Physics},
  author={Zhang, Xinxing and Ganteför, Gerd and Eichhorn, Bryan and Mayo, Dennis and Sawyer, William H and Gill, Ann F and Kandalam, Anil K. and Schnöckel, Hansgeorg and Bowen, Kit},
  note={Article Number: 074305}
}
kops.citation.iso690ZHANG, Xinxing, Gerd GANTEFÖR, Bryan EICHHORN, Dennis MAYO, William H SAWYER, Ann F GILL, Anil K. KANDALAM, Hansgeorg SCHNÖCKEL, Kit BOWEN, 2016. Low oxidation state aluminum-containing cluster anions: Cp∗AlnH−, n = 1–3. In: The Journal of Chemical Physics. 2016, 145(7), 074305. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4959847deu
kops.citation.iso690ZHANG, Xinxing, Gerd GANTEFÖR, Bryan EICHHORN, Dennis MAYO, William H SAWYER, Ann F GILL, Anil K. KANDALAM, Hansgeorg SCHNÖCKEL, Kit BOWEN, 2016. Low oxidation state aluminum-containing cluster anions: Cp∗AlnH−, n = 1–3. In: The Journal of Chemical Physics. 2016, 145(7), 074305. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4959847eng
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kops.sourcefieldThe Journal of Chemical Physics. 2016, <b>145</b>(7), 074305. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4959847deu
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kops.sourcefield.plainThe Journal of Chemical Physics. 2016, 145(7), 074305. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4959847eng
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source.periodicalTitleThe Journal of Chemical Physicseng

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