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Low oxidation state aluminum-containing cluster anions: Cp∗AlnH−, n = 1–3

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2016

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Zhang, Xinxing
Eichhorn, Bryan
Mayo, Dennis
Sawyer, William H
Gill, Ann F
Kandalam, Anil K.
Schnöckel, Hansgeorg
Bowen, Kit

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https://doi.org/10.1063/1.4959847
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The Journal of Chemical Physics. 2016, 145(7), 074305. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4959847

Zusammenfassung

Three new, low oxidation state, aluminum-containing cluster anions, CpAlnH(-), n = 1-3, were prepared via reactions between aluminum hydride cluster anions, AlnHm (-), and CpH ligands. These were characterized by mass spectrometry, anion photoelectron spectroscopy, and density functional theory based calculations. Agreement between the experimentally and theoretically determined vertical detachment energies and adiabatic detachment energies validated the computed geometrical structures. Reactions between aluminum hydride cluster anions and ligands provide a new avenue for discovering low oxidation state, ligated aluminum clusters.

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ISO 690ZHANG, Xinxing, Gerd GANTEFÖR, Bryan EICHHORN, Dennis MAYO, William H SAWYER, Ann F GILL, Anil K. KANDALAM, Hansgeorg SCHNÖCKEL, Kit BOWEN, 2016. Low oxidation state aluminum-containing cluster anions: Cp∗AlnH−, n = 1–3. In: The Journal of Chemical Physics. 2016, 145(7), 074305. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4959847
BibTex
@article{Zhang2016oxida-36947,
  year={2016},
  doi={10.1063/1.4959847},
  title={Low oxidation state aluminum-containing cluster anions: Cp<sup>∗</sup>Al<sub>n</sub>H<sup>−</sup>, n = 1–3},
  number={7},
  volume={145},
  issn={0021-9606},
  journal={The Journal of Chemical Physics},
  author={Zhang, Xinxing and Ganteför, Gerd and Eichhorn, Bryan and Mayo, Dennis and Sawyer, William H and Gill, Ann F and Kandalam, Anil K. and Schnöckel, Hansgeorg and Bowen, Kit},
  note={Article Number: 074305}
}
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