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Intramolecular Cobalt-Catalyzed [2+2+2] Cycloaddition of O-Protected Diyne-Cyanohydrins

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2010

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http://nbn-resolving.de/urn:nbn:de:bsz:352-125878
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https://doi.org/10.1055/s-0029-1219572
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Synlett. 2010, 2010(07), pp. 1051-1054. ISSN 0936-5214. Available under: doi: 10.1055/s-0029-1219572

Zusammenfassung

O-Protected cyanohydrins were found to serve as a source of the nitrile within the intramolecular cobalt-mediated [2+2+2] cycloaddition to pyridines. Several 6-substituted 1,2,3,4,7,8,9,10-octahydrophenanthridines were synthesized using this cycloaddition of diyne-cyanohydrins. By introduction a TMS group a divergent way to such phenanthridine derivatives was elaborated.

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540 Chemie

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cyanohydrin, cycloaddition, pyridines, alkynes, heterocycles

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ISO 690MEISSNER, Anja, Ulrich GROTH, 2010. Intramolecular Cobalt-Catalyzed [2+2+2] Cycloaddition of O-Protected Diyne-Cyanohydrins. In: Synlett. 2010, 2010(07), pp. 1051-1054. ISSN 0936-5214. Available under: doi: 10.1055/s-0029-1219572
BibTex
@article{Meiner2010Intra-12587,
  year={2010},
  doi={10.1055/s-0029-1219572},
  title={Intramolecular Cobalt-Catalyzed [2+2+2] Cycloaddition of O-Protected Diyne-Cyanohydrins},
  number={07},
  volume={2010},
  issn={0936-5214},
  journal={Synlett},
  pages={1051--1054},
  author={Meißner, Anja and Groth, Ulrich}
}
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