Morphogenesis of anisotropic nanoparticles : self-templating via non-classical, fibrillar Cd2Se intermediates

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A fibrillar, polymeric intermediate (Cd2Se)n was isolated from the synthesis of CdSe nanorods, which suggests that the reactants themselves can template anisotropic growth. It is shown that high monomer concentration is the principal factor favouring this reaction pathway. The intermediate is distinct from crystalline semiconductor or small clusters and is surprisingly temperature-stable below 250 °C.

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ISO 690WURMBRAND, Daniel, Jörg Wolfram Anselm FISCHER, Rose ROSENBERG, Klaus BOLDT, 2018. Morphogenesis of anisotropic nanoparticles : self-templating via non-classical, fibrillar Cd2Se intermediates. In: Chemical Communications : ChemComm. 2018, 54(53), pp. 7358-7361. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/c8cc02058b
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@article{Wurmbrand2018-06-28Morph-42866,
  year={2018},
  doi={10.1039/c8cc02058b},
  title={Morphogenesis of anisotropic nanoparticles : self-templating via non-classical, fibrillar Cd<sub>2</sub>Se intermediates},
  number={53},
  volume={54},
  issn={1359-7345},
  journal={Chemical Communications : ChemComm},
  pages={7358--7361},
  author={Wurmbrand, Daniel and Fischer, Jörg Wolfram Anselm and Rosenberg, Rose and Boldt, Klaus}
}
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