Publikation: Zinc(II)-Chloride Induced Thioalkylation of Aluminium Enolates : Enantioselective Synthesis of Estradiol-3-Methyl-17-tert-Butyl Diether
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1991
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Tetrahedron. 1991, 47(36), pp. 7583-7592. ISSN 0040-4020. Available under: doi: 10.1016/S0040-4020(01)88282-X
Zusammenfassung
Zinc(II)-chloride induced thioalkylation of the aluminium enolate 6 generated by conlugate reduction of the enone 5 leads - directly or via its trimethylsilylenol ether 6 - to alkylated hydrindanones 10 which are important intermediates in the synthesis of 19-norsteroids such as the title compound estradiol-3-methyl-17-tert-butyl diether 12
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GROTH, Ulrich, Thomas KOHLER, Thomas TAAPKEN, 1991. Zinc(II)-Chloride Induced Thioalkylation of Aluminium Enolates : Enantioselective Synthesis of Estradiol-3-Methyl-17-tert-Butyl Diether. In: Tetrahedron. 1991, 47(36), pp. 7583-7592. ISSN 0040-4020. Available under: doi: 10.1016/S0040-4020(01)88282-XBibTex
@article{Groth1991ZincI-9885, year={1991}, doi={10.1016/S0040-4020(01)88282-X}, title={Zinc(II)-Chloride Induced Thioalkylation of Aluminium Enolates : Enantioselective Synthesis of Estradiol-3-Methyl-17-tert-Butyl Diether}, number={36}, volume={47}, issn={0040-4020}, journal={Tetrahedron}, pages={7583--7592}, author={Groth, Ulrich and Kohler, Thomas and Taapken, Thomas} }
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