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Advances in the Synthesis and Characterization of Polypeptide-Based Hybrid Block Copolymers

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2004

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Dimitrov, Ivaylo
Kukula, Hildegard
Schlaad, Helmut

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https://doi.org/10.1002/masy.200451129
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Macromolecular Symposia. 2004, 215(1), pp. 383-393. ISSN 1022-1360. eISSN 1521-3900. Available under: doi: 10.1002/masy.200451129

Zusammenfassung

Linear polystyrene-block-poly(Z-L-lysine) copolymers with a very narrow molecular weight distribution (polydispersity index < 1.03) could be obtained via the ring-opening polymerization of Z-L-lysine-N-carboxyanhydride using ω-(primary amino hydrochloride)-polystyrenes as macroinitiators in N,N-dimethylformamide as the solvent at 40-80 °C. The block copolymer samples were analyzed by means of NMR, size exclusion chromatography, and analytical ultracentrifugation.

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540 Chemie

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ISO 690DIMITROV, Ivaylo, Hildegard KUKULA, Helmut CÖLFEN, Helmut SCHLAAD, 2004. Advances in the Synthesis and Characterization of Polypeptide-Based Hybrid Block Copolymers. In: Macromolecular Symposia. 2004, 215(1), pp. 383-393. ISSN 1022-1360. eISSN 1521-3900. Available under: doi: 10.1002/masy.200451129
BibTex
@article{Dimitrov2004Advan-40414,
  year={2004},
  doi={10.1002/masy.200451129},
  title={Advances in the Synthesis and Characterization of Polypeptide-Based Hybrid Block Copolymers},
  number={1},
  volume={215},
  issn={1022-1360},
  journal={Macromolecular Symposia},
  pages={383--393},
  author={Dimitrov, Ivaylo and Kukula, Hildegard and Cölfen, Helmut and Schlaad, Helmut}
}
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    <dcterms:abstract xml:lang="eng">Linear polystyrene-block-poly(Z-L-lysine) copolymers with a very narrow molecular weight distribution (polydispersity index &lt; 1.03) could be obtained via the ring-opening polymerization of Z-L-lysine-N-carboxyanhydride using ω-(primary amino hydrochloride)-polystyrenes as macroinitiators in N,N-dimethylformamide as the solvent at 40-80 °C. The block copolymer samples were analyzed by means of NMR, size exclusion chromatography, and analytical ultracentrifugation.</dcterms:abstract>
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