Publikation: Modulating Nucleation by Kosmotropes and Chaotropes : Testing the Waters
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2017
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Crystals. 2017, 7(10), 0302. eISSN 2073-4352. Available under: doi: 10.3390/cryst7100302
Zusammenfassung
Water is a fundamental solvent sustaining life, key to the conformations and equilibria associated with solute species. Emerging studies on nucleation and crystallization phenomena reveal that the dynamics of hydration associated with mineral precursors are critical in determining material formation and growth. With certain small molecules affecting the hydration and conformational stability of co-solutes, this study systematically explores the effects of these chaotropes and kosmotropes as well as certain sugar enantiomers on the early stages of calcium carbonate formation. These small molecules appear to modulate mineral nucleation in a class-dependent manner. The observed effects are finite in comparison to the established, strong interactions between charged polymers and intermediate mineral forms. Thus, perturbations to hydration dynamics of ion clusters by co-solute species can affect nucleation phenomena in a discernable manner.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
540 Chemie
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crystallization; nucleation; kosmotropes; chaotropes; small molecules; hydration
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RAO, Ashit, Denis GEBAUER, Helmut CÖLFEN, 2017. Modulating Nucleation by Kosmotropes and Chaotropes : Testing the Waters. In: Crystals. 2017, 7(10), 0302. eISSN 2073-4352. Available under: doi: 10.3390/cryst7100302BibTex
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year={2017},
doi={10.3390/cryst7100302},
title={Modulating Nucleation by Kosmotropes and Chaotropes : Testing the Waters},
number={10},
volume={7},
journal={Crystals},
author={Rao, Ashit and Gebauer, Denis and Cölfen, Helmut},
note={Article Number: 0302}
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