Publikation:

ansa-metallocene derivatives : XVIII. Chiral titanocene derivatives accessible from substituted dihydropentalene and azulene precursors

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Burger_239516.pdf
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1989

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Hund, Hans-Ulrich
Evertz, Kaspar

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http://nbn-resolving.de/urn:nbn:de:bsz:352-239516
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https://doi.org/10.1016/0022-328X(89)80004-X
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Published

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Journal of Organometallic Chemistry. 1989, 378(2), pp. 153-161. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(89)80004-X

Zusammenfassung

The product of an Mg/CCl4-induced reductive coupling of guaiazulene reacts with TiCl3·3THF to yield, after oxidation with HCl/O2, R,S-8,8′-biguaiazulenide titanium dichloride, which contains a CC bond between its two guaiazulenide ligand moieties. A similar reaction sequence starting from 3-phenyl-1,2-dihydropentalene gives unbridged R,S-bis(4-exo-phenyl-4H-5,6-dihydropentalenide)titanium dichloride.

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ISO 690BURGER, Peter, Hans-Ulrich HUND, Kaspar EVERTZ, Hans-Herbert BRINTZINGER, 1989. ansa-metallocene derivatives : XVIII. Chiral titanocene derivatives accessible from substituted dihydropentalene and azulene precursors. In: Journal of Organometallic Chemistry. 1989, 378(2), pp. 153-161. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(89)80004-X
BibTex
@article{Burger1989ansam-23951,
  year={1989},
  doi={10.1016/0022-328X(89)80004-X},
  title={ansa-metallocene derivatives : XVIII. Chiral titanocene derivatives accessible from substituted dihydropentalene and azulene precursors},
  number={2},
  volume={378},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={153--161},
  author={Burger, Peter and Hund, Hans-Ulrich and Evertz, Kaspar and Brintzinger, Hans-Herbert}
}
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