Publikation:

The gas phase reaction of iridium and iridium carbide anions with 2-hydoxyethylhydrazine (HEH)

Lade...
Vorschaubild

Dateien

Zu diesem Dokument gibt es keine Dateien.

Datum

2022

Autor:innen

Chiba, Tatsuya
Boatz, Jerry A.
Chambreau, Steven D.
Bowen, Kit H.

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

URI (zitierfähiger Link)
ArXiv-ID

Internationale Patentnummer

Angaben zur Forschungsförderung

Projekt

Open Access-Veröffentlichung
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

International Journal of Mass Spectrometry. Elsevier. 2022, 478, 116875. ISSN 1387-3806. eISSN 1873-2798. Available under: doi: 10.1016/j.ijms.2022.116875

Zusammenfassung

Understanding the chemistry of compounds that are similar to hydrazine has two advantages. First, it helps to identify less hazardous propellants to replace hydrazine as the most widely used monopropellant. And second, it helps to gain insight into the reaction mechanism that could be analogous to the decomposition of hydrazine into ammonia and nitrogen. Ionic liquids have already shown to be promising candidates to replace hydrazine. The molecule investigated in this study is 2-hydroxyethlyhydrazine (HOCH2CH2NHNH2; HEH), which is a neutral precursor to the ionic liquid 2-hydroxyethylhydrazinium nitrate (HEHN) and differs from hydrazine by the substitution of a hydrogen with a hydroxyethyl group. Gas phase photoelectron spectroscopy and density functional theory were used to examine the reaction between a HEH molecule and an Ir anion as well as with IrC. Suggested by the experimental and theoretical data, Ir and IrC react with HEH and can attack the C–N, C–O, N–N, C–H and the C–C bond in HEH.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
530 Physik

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Zugehörige Datensätze in KOPS

Zitieren

ISO 690BLANKENHORN, Moritz, Tatsuya CHIBA, Jerry A. BOATZ, Steven D. CHAMBREAU, Gerd GANTEFÖR, Kit H. BOWEN, 2022. The gas phase reaction of iridium and iridium carbide anions with 2-hydoxyethylhydrazine (HEH). In: International Journal of Mass Spectrometry. Elsevier. 2022, 478, 116875. ISSN 1387-3806. eISSN 1873-2798. Available under: doi: 10.1016/j.ijms.2022.116875
BibTex
@article{Blankenhorn2022phase-57833,
  year={2022},
  doi={10.1016/j.ijms.2022.116875},
  title={The gas phase reaction of iridium and iridium carbide anions with 2-hydoxyethylhydrazine (HEH)},
  volume={478},
  issn={1387-3806},
  journal={International Journal of Mass Spectrometry},
  author={Blankenhorn, Moritz and Chiba, Tatsuya and Boatz, Jerry A. and Chambreau, Steven D. and Ganteför, Gerd and Bowen, Kit H.},
  note={Article Number: 116875}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/57833">
    <dc:creator>Boatz, Jerry A.</dc:creator>
    <dc:creator>Bowen, Kit H.</dc:creator>
    <dc:contributor>Chiba, Tatsuya</dc:contributor>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dc:creator>Chiba, Tatsuya</dc:creator>
    <dc:creator>Ganteför, Gerd</dc:creator>
    <dcterms:abstract xml:lang="eng">Understanding the chemistry of compounds that are similar to hydrazine has two advantages. First, it helps to identify less hazardous propellants to replace hydrazine as the most widely used monopropellant. And second, it helps to gain insight into the reaction mechanism that could be analogous to the decomposition of hydrazine into ammonia and nitrogen. Ionic liquids have already shown to be promising candidates to replace hydrazine. The molecule investigated in this study is 2-hydroxyethlyhydrazine (HOCH&lt;sub&gt;2&lt;/sub&gt;CH&lt;sub&gt;2&lt;/sub&gt;NHNH&lt;sub&gt;2&lt;/sub&gt;; HEH), which is a neutral precursor to the ionic liquid 2-hydroxyethylhydrazinium nitrate (HEHN) and differs from hydrazine by the substitution of a hydrogen with a hydroxyethyl group. Gas phase photoelectron spectroscopy and density functional theory were used to examine the reaction between a HEH molecule and an Ir&lt;sup&gt;−&lt;/sup&gt; anion as well as with IrC&lt;sup&gt;−&lt;/sup&gt;. Suggested by the experimental and theoretical data, Ir&lt;sup&gt;−&lt;/sup&gt; and IrC&lt;sup&gt;−&lt;/sup&gt; react with HEH and can attack the C–N, C–O, N–N, C–H and the C–C bond in HEH.</dcterms:abstract>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:contributor>Ganteför, Gerd</dc:contributor>
    <dcterms:title>The gas phase reaction of iridium and iridium carbide anions with 2-hydoxyethylhydrazine (HEH)</dcterms:title>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:contributor>Chambreau, Steven D.</dc:contributor>
    <dc:contributor>Boatz, Jerry A.</dc:contributor>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2022-06-23T13:33:44Z</dcterms:available>
    <dc:contributor>Bowen, Kit H.</dc:contributor>
    <dc:creator>Blankenhorn, Moritz</dc:creator>
    <dc:language>eng</dc:language>
    <dc:contributor>Blankenhorn, Moritz</dc:contributor>
    <dcterms:issued>2022</dcterms:issued>
    <dc:creator>Chambreau, Steven D.</dc:creator>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2022-06-23T13:33:44Z</dc:date>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/57833"/>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
Begutachtet
Unbekannt
Diese Publikation teilen