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8-Sila-4-stanna-s-tetrahydroindacenes as synthons for Me2Si-bridged zirconocenes : formation from biscyclopentadienyl silanes by reaction with aminostannanes

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Huettenhofer_238581.pdf
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2002

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Hüttenhofer, Mario
Schaper, Frank

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http://nbn-resolving.de/urn:nbn:de:bsz:352-238581
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https://doi.org/10.1016/S0022-328X(02)01775-8
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Published

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Journal of Organometallic Chemistry. 2002, 660(1), pp. 85-90. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(02)01775-8

Zusammenfassung

Alkyl-substituted bis(cyclopentadienyl)dimethylsilanes react with Me2Sn(NEt2)2 and with (Me2N)4Sn to yield correspondingly substituted, meso-configurated RS-8-sila-4-stanna-s-tetrahydroindacene and axially symmetric RR,SS-4-spiro-bis(8-sila-4-stanna-s-tetrahydroindacene) compounds, respectively, which are stereoselectively converted by reaction with ZrCl4 to the corresponding meso- and rac-configurated ansa-zirconocene complexes.

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540 Chemie

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ISO 690HÜTTENHOFER, Mario, Frank SCHAPER, Hans-Herbert BRINTZINGER, 2002. 8-Sila-4-stanna-s-tetrahydroindacenes as synthons for Me2Si-bridged zirconocenes : formation from biscyclopentadienyl silanes by reaction with aminostannanes. In: Journal of Organometallic Chemistry. 2002, 660(1), pp. 85-90. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(02)01775-8
BibTex
@article{Huttenhofer20028Sila-23858,
  year={2002},
  doi={10.1016/S0022-328X(02)01775-8},
  title={8-Sila-4-stanna-s-tetrahydroindacenes as synthons for Me<sub>2</sub>Si-bridged zirconocenes : formation from biscyclopentadienyl silanes by reaction with aminostannanes},
  number={1},
  volume={660},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={85--90},
  author={Hüttenhofer, Mario and Schaper, Frank and Brintzinger, Hans-Herbert}
}
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