Publikation: 8-Sila-4-stanna-s-tetrahydroindacenes as synthons for Me2Si-bridged zirconocenes : formation from biscyclopentadienyl silanes by reaction with aminostannanes
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Journal of Organometallic Chemistry. 2002, 660(1), pp. 85-90. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(02)01775-8
Zusammenfassung
Alkyl-substituted bis(cyclopentadienyl)dimethylsilanes react with Me2Sn(NEt2)2 and with (Me2N)4Sn to yield correspondingly substituted, meso-configurated RS-8-sila-4-stanna-s-tetrahydroindacene and axially symmetric RR,SS-4-spiro-bis(8-sila-4-stanna-s-tetrahydroindacene) compounds, respectively, which are stereoselectively converted by reaction with ZrCl4 to the corresponding meso- and rac-configurated ansa-zirconocene complexes.
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HÜTTENHOFER, Mario, Frank SCHAPER, Hans-Herbert BRINTZINGER, 2002. 8-Sila-4-stanna-s-tetrahydroindacenes as synthons for Me2Si-bridged zirconocenes : formation from biscyclopentadienyl silanes by reaction with aminostannanes. In: Journal of Organometallic Chemistry. 2002, 660(1), pp. 85-90. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(02)01775-8BibTex
@article{Huttenhofer20028Sila-23858, year={2002}, doi={10.1016/S0022-328X(02)01775-8}, title={8-Sila-4-stanna-s-tetrahydroindacenes as synthons for Me<sub>2</sub>Si-bridged zirconocenes : formation from biscyclopentadienyl silanes by reaction with aminostannanes}, number={1}, volume={660}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={85--90}, author={Hüttenhofer, Mario and Schaper, Frank and Brintzinger, Hans-Herbert} }
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