CdSe/CdS—Conjugated Polymer Core–Shell Hybrid Nanoparticles by a Grafting-From Approach

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2016
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ACS Macro Letters. 2016, 5(7), pp. 786-789. ISSN 2161-1653. eISSN 2161-1653. Available under: doi: 10.1021/acsmacrolett.6b00323
Zusammenfassung

Hybrid particles consisting of II–VI semiconductor quantum dots and conjugated polymers are increasingly relevant, but access is limited by the usual step-growth nature of polymer formation. We report on a grafting-from approach by controlled Pd(II)-mediated polymerization to yield CdSe/CdS nanocrystals with a defined number of polyfluorene chains grown from their surface, as concluded from MALDI-TOF analysis and quantitative end-capping. Further studies underline the importance of matching the monomers’ and the surface-bound initiators’ reactivity.

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ISO 690DE ROO, Tjaard, Steffen HUBER, Stefan MECKING, 2016. CdSe/CdS—Conjugated Polymer Core–Shell Hybrid Nanoparticles by a Grafting-From Approach. In: ACS Macro Letters. 2016, 5(7), pp. 786-789. ISSN 2161-1653. eISSN 2161-1653. Available under: doi: 10.1021/acsmacrolett.6b00323
BibTex
@article{deRoo2016-06-14CdSeC-34762,
  year={2016},
  doi={10.1021/acsmacrolett.6b00323},
  title={CdSe/CdS—Conjugated Polymer Core–Shell Hybrid Nanoparticles by a Grafting-From Approach},
  number={7},
  volume={5},
  issn={2161-1653},
  journal={ACS Macro Letters},
  pages={786--789},
  author={de Roo, Tjaard and Huber, Steffen and Mecking, Stefan}
}
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