CdSe/CdS—Conjugated Polymer Core–Shell Hybrid Nanoparticles by a Grafting-From Approach
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ACS Macro Letters. 2016, 5(7), pp. 786-789. ISSN 2161-1653. eISSN 2161-1653. Available under: doi: 10.1021/acsmacrolett.6b00323
Zusammenfassung
Hybrid particles consisting of II–VI semiconductor quantum dots and conjugated polymers are increasingly relevant, but access is limited by the usual step-growth nature of polymer formation. We report on a grafting-from approach by controlled Pd(II)-mediated polymerization to yield CdSe/CdS nanocrystals with a defined number of polyfluorene chains grown from their surface, as concluded from MALDI-TOF analysis and quantitative end-capping. Further studies underline the importance of matching the monomers’ and the surface-bound initiators’ reactivity.
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DE ROO, Tjaard, Steffen HUBER, Stefan MECKING, 2016. CdSe/CdS—Conjugated Polymer Core–Shell Hybrid Nanoparticles by a Grafting-From Approach. In: ACS Macro Letters. 2016, 5(7), pp. 786-789. ISSN 2161-1653. eISSN 2161-1653. Available under: doi: 10.1021/acsmacrolett.6b00323BibTex
@article{deRoo2016-06-14CdSeC-34762, year={2016}, doi={10.1021/acsmacrolett.6b00323}, title={CdSe/CdS—Conjugated Polymer Core–Shell Hybrid Nanoparticles by a Grafting-From Approach}, number={7}, volume={5}, issn={2161-1653}, journal={ACS Macro Letters}, pages={786--789}, author={de Roo, Tjaard and Huber, Steffen and Mecking, Stefan} }
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