Publikation:

Aluminum hydride cluster cations : a mass spectrometric and computational study

Vorschaubild

Dateien

Zu diesem Dokument gibt es keine Dateien.

Datum

2016

Autor:innen

Fontenot, Victoria
Kiran, Boggavarapu
Zhang, Xinxing
Wang, Haopeng
Bowen, Kit

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

URI (zitierfähiger Link)
DOI (zitierfähiger Link)
https://doi.org/10.1016/j.ijms.2016.08.004
ArXiv-ID

Internationale Patentnummer

Angaben zur Forschungsförderung

Projekt

Open Access-Veröffentlichung

Sammlungen

Physik: Publikationen
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

International Journal of Mass Spectrometry. 2016, 408, pp. 56-61. ISSN 1387-3806. eISSN 1873-2798. Available under: doi: 10.1016/j.ijms.2016.08.004

Zusammenfassung

A combined study using mass spectrometry and density functional theory (DFT) was conducted to investigate aluminum hydride cluster cations, AlnHm+ (1 ≤ n ≤ 5, 0 ≤ m ≤ 12). The mass spectra revealed about 20 previously-unknown aluminum hydride cluster cations. Among these species, several showed high mass spectral intensities, suggesting that they had unusual stabilities. Density functional theory calculations were conducted to investigate the geometric structures of these clusters. Many of these clusters can be viewed as being composed of smaller, stable units, such as Al+, AlH3, Al2+/0, H+ and H2.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
530 Physik

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Zugehörige Datensätze in KOPS

Zitieren

ISO 690FONTENOT, Victoria, Boggavarapu KIRAN, Xinxing ZHANG, Haopeng WANG, Gerd GANTEFÖR, Kit BOWEN, 2016. Aluminum hydride cluster cations : a mass spectrometric and computational study. In: International Journal of Mass Spectrometry. 2016, 408, pp. 56-61. ISSN 1387-3806. eISSN 1873-2798. Available under: doi: 10.1016/j.ijms.2016.08.004
BibTex
@article{Fontenot2016-09Alumi-35397,
  year={2016},
  doi={10.1016/j.ijms.2016.08.004},
  title={Aluminum hydride cluster cations : a mass spectrometric and computational study},
  volume={408},
  issn={1387-3806},
  journal={International Journal of Mass Spectrometry},
  pages={56--61},
  author={Fontenot, Victoria and Kiran, Boggavarapu and Zhang, Xinxing and Wang, Haopeng and Ganteför, Gerd and Bowen, Kit}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/35397">
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dc:contributor>Fontenot, Victoria</dc:contributor>
    <dc:creator>Ganteför, Gerd</dc:creator>
    <dcterms:title>Aluminum hydride cluster cations : a mass spectrometric and computational study</dcterms:title>
    <dc:contributor>Zhang, Xinxing</dc:contributor>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2016-09-23T09:38:44Z</dcterms:available>
    <dc:creator>Bowen, Kit</dc:creator>
    <dc:contributor>Wang, Haopeng</dc:contributor>
    <dcterms:abstract xml:lang="eng">A combined study using mass spectrometry and density functional theory (DFT) was conducted to investigate aluminum hydride cluster cations, Al&lt;sub&gt;n&lt;/sub&gt;H&lt;sub&gt;m&lt;/sub&gt;&lt;sup&gt;+&lt;/sup&gt; (1 ≤ n ≤ 5, 0 ≤ m ≤ 12). The mass spectra revealed about 20 previously-unknown aluminum hydride cluster cations. Among these species, several showed high mass spectral intensities, suggesting that they had unusual stabilities. Density functional theory calculations were conducted to investigate the geometric structures of these clusters. Many of these clusters can be viewed as being composed of smaller, stable units, such as Al&lt;sup&gt;+&lt;/sup&gt;, AlH&lt;sub&gt;3&lt;/sub&gt;, Al&lt;sub&gt;2&lt;/sub&gt;&lt;sup&gt;+/0&lt;/sup&gt;, H&lt;sup&gt;+&lt;/sup&gt; and H&lt;sub&gt;2&lt;/sub&gt;.</dcterms:abstract>
    <dc:creator>Kiran, Boggavarapu</dc:creator>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2016-09-23T09:38:44Z</dc:date>
    <dc:contributor>Kiran, Boggavarapu</dc:contributor>
    <dc:contributor>Ganteför, Gerd</dc:contributor>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dc:language>eng</dc:language>
    <dc:creator>Fontenot, Victoria</dc:creator>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:creator>Zhang, Xinxing</dc:creator>
    <dc:contributor>Bowen, Kit</dc:contributor>
    <dc:creator>Wang, Haopeng</dc:creator>
    <dcterms:issued>2016-09</dcterms:issued>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/35397"/>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
Begutachtet
Diese Publikation teilen