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Pyrolytic carbon layers : an electron spin resonance analysis

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2003

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Hüttinger, Klaus J.
Dormann, Elmar

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https://doi.org/10.1016/S0008-6223(02)00397-4
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Chemie: Publikationen
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Carbon. 2003, 41(4), pp. 773-783. ISSN 0008-6223. eISSN 1873-3891. Available under: doi: 10.1016/S0008-6223(02)00397-4

Zusammenfassung

Chemical vapour infiltration is simulated by deposition of pyrolytic carbon on planar boron nitride substrates and carbon fibers in a hot-wall tubular reactor at about 1100 °C for varied pressure and flow-velocity of methane. The degree of orientation of the deposited graphite-like domains can be monitored via orientation and temperature dependence of the electron spin resonance parameters (g-tensor, linewidth). The electronic structure of the localized defects and conduction electrons is accessible by a quantitative modelling of these parameters. The interaction of the built-in hydrogen atoms with the unpaired electron spins is analysed by electron–proton spin double resonance technique (Overhauser shift)

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Fachgebiet (DDC)
540 Chemie

Schlagwörter

A. Pyrolytic carbon; B. Chemical vapor deposition; Chemical vapor infiltration; C. Electron paramagnetic resonance

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ISO 690DRESCHER, Malte, Klaus J. HÜTTINGER, Elmar DORMANN, 2003. Pyrolytic carbon layers : an electron spin resonance analysis. In: Carbon. 2003, 41(4), pp. 773-783. ISSN 0008-6223. eISSN 1873-3891. Available under: doi: 10.1016/S0008-6223(02)00397-4
BibTex
@article{Drescher2003Pyrol-40198,
  year={2003},
  doi={10.1016/S0008-6223(02)00397-4},
  title={Pyrolytic carbon layers : an electron spin resonance analysis},
  number={4},
  volume={41},
  issn={0008-6223},
  journal={Carbon},
  pages={773--783},
  author={Drescher, Malte and Hüttinger, Klaus J. and Dormann, Elmar}
}
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