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From Oleo Chemicals to Polymer : Bis-hydroaminomethylation as a Tool for the Preparation of a Synthetic Polymer from Renewables

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2016

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Seidensticker, Thomas
Diederichs, Christopher
von Dincklage, Jork Jonas
Vorholt, Andreas J.

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https://doi.org/10.1002/cctc.201600629
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ChemCatChem. 2016, 8(18), pp. 2890-2893. ISSN 1867-3880. eISSN 1867-3899. Available under: doi: 10.1002/cctc.201600629

Zusammenfassung

Resource-efficient bis-hydroaminomethylation of the castor oil derived renewables methyl 10-undecenoate and 10-undecene-1-ol with piperazine furnished linear, bifunctional molecules. A structured and sustainable path towards a novel polyester from these monomers was developed. Key to success was the selective crystallization of the linear product directly from the crude reaction mixture in >98 % purity. Additionally, with this methodology, the homogeneous Rh catalyst was retained in the supernatant and was successfully recycled. Finally, polycondensation yielded a novel piperazine-linked polyester.

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ISO 690SEIDENSTICKER, Thomas, Hanna BUSCH, Christopher DIEDERICHS, Jork Jonas VON DINCKLAGE, Andreas J. VORHOLT, 2016. From Oleo Chemicals to Polymer : Bis-hydroaminomethylation as a Tool for the Preparation of a Synthetic Polymer from Renewables. In: ChemCatChem. 2016, 8(18), pp. 2890-2893. ISSN 1867-3880. eISSN 1867-3899. Available under: doi: 10.1002/cctc.201600629
BibTex
@article{Seidensticker2016Chemi-37776,
  year={2016},
  doi={10.1002/cctc.201600629},
  title={From Oleo Chemicals to Polymer : Bis-hydroaminomethylation as a Tool for the Preparation of a Synthetic Polymer from Renewables},
  number={18},
  volume={8},
  issn={1867-3880},
  journal={ChemCatChem},
  pages={2890--2893},
  author={Seidensticker, Thomas and Busch, Hanna and Diederichs, Christopher and von Dincklage, Jork Jonas and Vorholt, Andreas J.}
}
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