Publikation: Criticality and phase separation in a two-dimensional binary colloidal fluid induced by the solvent critical behavior
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2011
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EPL : Europhysics Letters. 2011, 96(2), 28005. ISSN 0295-5075. eISSN 1286-4854. Available under: doi: 10.1209/0295-5075/96/28005
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We present an experimental and theoretical study of the phase behavior of a binary mixture of colloids with opposite adsorption preferences in a critical solvent. As a result of the attractive and repulsive critical Casimir forces, the critical fluctuations of the solvent lead to a further critical point in the colloidal system, i.e. to a critical colloidal-liquid–colloidal-liquid demixing phase transition which is controlled by the solvent temperature. Our experimental findings are in good agreement with calculations based on a simple approximation for the free energy of the system.
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530 Physik
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ZVYAGOLSKAYA, Olga, Andrew J. ARCHER, Clemens BECHINGER, 2011. Criticality and phase separation in a two-dimensional binary colloidal fluid induced by the solvent critical behavior. In: EPL : Europhysics Letters. 2011, 96(2), 28005. ISSN 0295-5075. eISSN 1286-4854. Available under: doi: 10.1209/0295-5075/96/28005BibTex
@article{Zvyagolskaya2011-10-01Criti-39380, year={2011}, doi={10.1209/0295-5075/96/28005}, title={Criticality and phase separation in a two-dimensional binary colloidal fluid induced by the solvent critical behavior}, number={2}, volume={96}, issn={0295-5075}, journal={EPL : Europhysics Letters}, author={Zvyagolskaya, Olga and Archer, Andrew J. and Bechinger, Clemens}, note={Article Number: 28005} }
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