Publikation:

Aqueous Keto-Polyethylene Dispersions from Catalytic Copolymerization of Ethylene and Carbon Monoxide in Water

Lade...
Vorschaubild

Dateien

Baur_2-1644ziz9xxthd.pdf
Baur_2-1644ziz9xxthd.pdfGröße: 3.14 MBDownloads: 5

Datum

2024

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

ArXiv-ID

Internationale Patentnummer

Link zur Lizenz

Angaben zur Forschungsförderung

European Union (EU): 832480

Projekt

Open Access-Veröffentlichung
Open Access Hybrid
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

ACS Macro Letters. ACS Publications. 2024, 13(7), S. 841-846. eISSN 2161-1653. Verfügbar unter: doi: 10.1021/acsmacrolett.4c00313

Zusammenfassung

Water-soluble [P,O]Ni(II) catalysts enable the direct catalytic nonalternating copolymerization of fundamental comonomers ethylene and carbon monoxide (CO) in water as an environmentally friendly reaction medium. This yields stable aqueous dispersions of high molecular weight polyethylene containing ∼1 mol % of largely isolated in-chain keto groups in the form of particles with sizes between 100 nm and 1 μm. The intermediate species of chain growth resulting from incorporation of polar comonomers are amenable to specific chain termination pathways in conjunction with water.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Zugehörige Datensätze in KOPS

Zitieren

ISO 690BAUR, Maximilian, Rosa HABÉ, Stefan MECKING, 2024. Aqueous Keto-Polyethylene Dispersions from Catalytic Copolymerization of Ethylene and Carbon Monoxide in Water. In: ACS Macro Letters. ACS Publications. 2024, 13(7), S. 841-846. eISSN 2161-1653. Verfügbar unter: doi: 10.1021/acsmacrolett.4c00313
BibTex
@article{Baur2024Aqueo-70422,
  year={2024},
  doi={10.1021/acsmacrolett.4c00313},
  title={Aqueous Keto-Polyethylene Dispersions from Catalytic Copolymerization of Ethylene and Carbon Monoxide in Water},
  number={7},
  volume={13},
  journal={ACS Macro Letters},
  pages={841--846},
  author={Baur, Maximilian and Habé, Rosa and Mecking, Stefan}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/70422">
    <dcterms:title>Aqueous Keto-Polyethylene Dispersions from Catalytic Copolymerization of Ethylene and Carbon Monoxide in Water</dcterms:title>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/70422/1/Baur_2-1644ziz9xxthd.pdf"/>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/70422"/>
    <dc:contributor>Baur, Maximilian</dc:contributor>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:rights>Attribution 4.0 International</dc:rights>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2024-07-19T04:43:35Z</dc:date>
    <dcterms:rights rdf:resource="http://creativecommons.org/licenses/by/4.0/"/>
    <dc:contributor>Habé, Rosa</dc:contributor>
    <dc:contributor>Mecking, Stefan</dc:contributor>
    <dcterms:abstract>Water-soluble [P,O]Ni(II) catalysts enable the direct catalytic nonalternating copolymerization of fundamental comonomers ethylene and carbon monoxide (CO) in water as an environmentally friendly reaction medium. This yields stable aqueous dispersions of high molecular weight polyethylene containing ∼1 mol % of largely isolated in-chain keto groups in the form of particles with sizes between 100 nm and 1 μm. The intermediate species of chain growth resulting from incorporation of polar comonomers are amenable to specific chain termination pathways in conjunction with water.</dcterms:abstract>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/70422/1/Baur_2-1644ziz9xxthd.pdf"/>
    <dc:language>eng</dc:language>
    <dc:creator>Habé, Rosa</dc:creator>
    <dc:creator>Baur, Maximilian</dc:creator>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2024-07-19T04:43:35Z</dcterms:available>
    <dc:creator>Mecking, Stefan</dc:creator>
    <dcterms:issued>2024</dcterms:issued>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
Begutachtet
Unbekannt
Diese Publikation teilen