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Single-Step Catalytic Upgrading of Microalgae Biomass

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2018

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https://doi.org/10.1021/acssuschemeng.8b02939
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Chemie: Publikationen
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Published

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ACS Sustainable Chemistry & Engineering. 2018, 6(9), pp. 11219-11221. eISSN 2168-0485. Available under: doi: 10.1021/acssuschemeng.8b02939

Zusammenfassung

A direct catalytic upgrading on as-cultivated microalgae biomass is demonstrated. Via CO-free alkoxycarbonylation of the contained lipids with the use of formates, diesters were produced in high conversion and selectivity from monounsaturated fatty acids from Phaeodactylum tricornutum microalgae. Via this procedure, extraction and functionalization occur in one step, circumventing the need for separate workup procedures of the biomass. The products are valuable building blocks for renewable polyester materials.

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Fachgebiet (DDC)
540 Chemie

Schlagwörter

Carbonylation; Catalysis; Diatoms; Fatty acids; Lipids; Palladium; Phaeodactylum tricornutum; Sustainable process

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ISO 690PINGEN, Dennis, Nele KLINKENBERG, Stefan MECKING, 2018. Single-Step Catalytic Upgrading of Microalgae Biomass. In: ACS Sustainable Chemistry & Engineering. 2018, 6(9), pp. 11219-11221. eISSN 2168-0485. Available under: doi: 10.1021/acssuschemeng.8b02939
BibTex
@article{Pingen2018-09-04Singl-43379,
  year={2018},
  doi={10.1021/acssuschemeng.8b02939},
  title={Single-Step Catalytic Upgrading of Microalgae Biomass},
  number={9},
  volume={6},
  journal={ACS Sustainable Chemistry & Engineering},
  pages={11219--11221},
  author={Pingen, Dennis and Klinkenberg, Nele and Mecking, Stefan}
}
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