Publikation: Five-Membered 2-Methylene-2,3-dihydro Heterocycles from Ruthenium Butatrienylidene Intermediates and 2-(Dimethylamino)methyl-Substituted Furans, Thiophenes, and Selenophenes
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Organometallics. 2003, 22(16), pp. 3171-3174. ISSN 0276-7333. Available under: doi: 10.1021/om030317i
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Trapping of the primary butatrienylidene intermediate trans-[Cl(dppm)2RuCCCCH2]+ with five-membered 2-(dimethylamino)methyl-substituted heterocycles provides an easy and efficient route to aminoallenylidene complexes with appended 2-methylene-2,3-dihydrofuran, -thiophene, or -selenophene moieties. Upon warming or acid catalysis isomerization to the aromatic 2-methylated isomers is observed.
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HARBORT, Ralf-Christoph, Stephan HARTMANN, Rainer F. WINTER, Karl Wilhelm KLINKHAMMER, 2003. Five-Membered 2-Methylene-2,3-dihydro Heterocycles from Ruthenium Butatrienylidene Intermediates and 2-(Dimethylamino)methyl-Substituted Furans, Thiophenes, and Selenophenes. In: Organometallics. 2003, 22(16), pp. 3171-3174. ISSN 0276-7333. Available under: doi: 10.1021/om030317iBibTex
@article{Harbort2003FiveM-13836, year={2003}, doi={10.1021/om030317i}, title={Five-Membered 2-Methylene-2,3-dihydro Heterocycles from Ruthenium Butatrienylidene Intermediates and 2-(Dimethylamino)methyl-Substituted Furans, Thiophenes, and Selenophenes}, number={16}, volume={22}, issn={0276-7333}, journal={Organometallics}, pages={3171--3174}, author={Harbort, Ralf-Christoph and Hartmann, Stephan and Winter, Rainer F. and Klinkhammer, Karl Wilhelm} }
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