Publikation:

Effect of Charge Assisted Hydrogen Bonds on Single Molecule Electron Transport

Vorschaubild

Dateien

Zu diesem Dokument gibt es keine Dateien.

Datum

2019

Autor:innen

Sacchetti, Valentina
Ramos-Soriano, Javier
Illescas, Beatriz M.
González, M. Teresa
Palomino-Ruiz, Lucía
Marquez, Irene R.
Leary, Edmund
Rubio-Bollinger, Gabino
2 mehr anzeigen

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

URI (zitierfähiger Link)
DOI (zitierfähiger Link)
https://doi.org/10.1021/acs.jpcc.9b06850
ArXiv-ID

Internationale Patentnummer

Angaben zur Forschungsförderung

Projekt

Open Access-Veröffentlichung

Sammlungen

Physik: Publikationen
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

The Journal of Physical Chemistry C. 2019, 123(48), pp. 29386-29393. ISSN 1932-7447. eISSN 1932-7455. Available under: doi: 10.1021/acs.jpcc.9b06850

Zusammenfassung

The effect of the in-bone presence of charge assisted hydro-gen bonds in the conductance of single-molecule junctions has been studied by the scanning-tunneling microscope break-junction (STMBJ) technique. In particular two amidinium-carboxylate supramolecular complexes of differ-ent length have been tested. We observed that the ionic character that gives extra stability to the charge assisted hydrogen bond is however hindering the electron transport through the complexes. Theoretical calculations using the DFT+ method indicate that both the HOMO and LUMO of the complexes are fully localized in only one of the moieties of the complex explaining the low single molecular conductance of the compounds.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
530 Physik

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Zugehörige Datensätze in KOPS

Zitieren

ISO 690SACCHETTI, Valentina, Javier RAMOS-SORIANO, Beatriz M. ILLESCAS, M. Teresa GONZÁLEZ, Dongzhe LI, Lucía PALOMINO-RUIZ, Irene R. MARQUEZ, Edmund LEARY, Gabino RUBIO-BOLLINGER, Fabian PAULY, Nicolás AGRAÏT, Nazario MARTÍN, 2019. Effect of Charge Assisted Hydrogen Bonds on Single Molecule Electron Transport. In: The Journal of Physical Chemistry C. 2019, 123(48), pp. 29386-29393. ISSN 1932-7447. eISSN 1932-7455. Available under: doi: 10.1021/acs.jpcc.9b06850
BibTex
@article{Sacchetti2019-12-05Effec-47484,
  year={2019},
  doi={10.1021/acs.jpcc.9b06850},
  title={Effect of Charge Assisted Hydrogen Bonds on Single Molecule Electron Transport},
  number={48},
  volume={123},
  issn={1932-7447},
  journal={The Journal of Physical Chemistry C},
  pages={29386--29393},
  author={Sacchetti, Valentina and Ramos-Soriano, Javier and Illescas, Beatriz M. and González, M. Teresa and Li, Dongzhe and Palomino-Ruiz, Lucía and Marquez, Irene R. and Leary, Edmund and Rubio-Bollinger, Gabino and Pauly, Fabian and Agraït, Nicolás and Martín, Nazario}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/47484">
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dc:creator>Marquez, Irene R.</dc:creator>
    <dc:creator>Pauly, Fabian</dc:creator>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2019-11-13T13:53:49Z</dc:date>
    <dc:language>eng</dc:language>
    <dc:contributor>Sacchetti, Valentina</dc:contributor>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/47484"/>
    <dc:creator>González, M. Teresa</dc:creator>
    <dc:contributor>Rubio-Bollinger, Gabino</dc:contributor>
    <dc:contributor>González, M. Teresa</dc:contributor>
    <dc:creator>Ramos-Soriano, Javier</dc:creator>
    <dc:contributor>Martín, Nazario</dc:contributor>
    <dcterms:title>Effect of Charge Assisted Hydrogen Bonds on Single Molecule Electron Transport</dcterms:title>
    <dc:creator>Martín, Nazario</dc:creator>
    <dc:creator>Li, Dongzhe</dc:creator>
    <dc:contributor>Ramos-Soriano, Javier</dc:contributor>
    <dc:creator>Leary, Edmund</dc:creator>
    <dc:creator>Agraït, Nicolás</dc:creator>
    <dc:contributor>Leary, Edmund</dc:contributor>
    <dc:creator>Palomino-Ruiz, Lucía</dc:creator>
    <dcterms:abstract xml:lang="eng">The effect of the in-bone presence of charge assisted hydro-gen bonds in the conductance of single-molecule junctions has been studied by the scanning-tunneling microscope break-junction (STMBJ) technique. In particular two amidinium-carboxylate supramolecular complexes of differ-ent length have been tested. We observed that the ionic character that gives extra stability to the charge assisted hydrogen bond is however hindering the electron transport through the complexes. Theoretical calculations using the DFT+ method indicate that both the HOMO and LUMO of the complexes are fully localized in only one of the moieties of the complex explaining the low single molecular conductance of the compounds.</dcterms:abstract>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dcterms:issued>2019-12-05</dcterms:issued>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:contributor>Palomino-Ruiz, Lucía</dc:contributor>
    <dc:contributor>Li, Dongzhe</dc:contributor>
    <dc:contributor>Illescas, Beatriz M.</dc:contributor>
    <dc:creator>Rubio-Bollinger, Gabino</dc:creator>
    <dc:contributor>Marquez, Irene R.</dc:contributor>
    <dc:contributor>Pauly, Fabian</dc:contributor>
    <dc:contributor>Agraït, Nicolás</dc:contributor>
    <dc:creator>Sacchetti, Valentina</dc:creator>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2019-11-13T13:53:49Z</dcterms:available>
    <dc:creator>Illescas, Beatriz M.</dc:creator>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
Begutachtet
Ja
Diese Publikation teilen