Publikation: Total Synthesis of Ervatamia Alkaloids
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2023
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Zusammenfassung
This work discusses an enantioselective total synthesis of Ervatamia alkaloids. It relies on an enzyme-catalyzed desymmetrization approach for the installation of chirality. The indole moiety is introduced by a palladium catalyzed C-H activation at a cyclopropane. The cyclopropane is converted into the cyclohepta[b]indole structure of the natural products by a divinylcyclopropane-cycloheptadiene rearrangement. The piperidine moiety is closed by Heck-reaction.
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Fachgebiet (DDC)
540 Chemie
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Total Synthesis, Indole Alkaloids, C-H Activation, Electrocyclic Reactions, Heck-Reaction, Enzymatic Desymmetrization
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GAMERDINGER, Paul, 2023. Total Synthesis of Ervatamia Alkaloids [Dissertation]. Konstanz: University of KonstanzBibTex
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Prüfungsdatum der Dissertation
March 1, 2023
Hochschulschriftenvermerk
Konstanz, Univ., Diss., 2023
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