Publikation:

Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule

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Scheer.pdf
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2007

Autor:innen

Scheer, Manfred
Schindler, Andrea
Merkle, Roger
Johnson, Brian P.
Anson, Christopher E.
Virovets, Alexander V.

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http://nbn-resolving.de/urn:nbn:de:bsz:352-137980
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https://doi.org/10.1021/ja075926m
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Published

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Journal of the American Chemical Society. 2007, 129(44), pp. 13386-13387. ISSN 0002-7863. Available under: doi: 10.1021/ja075926m

Zusammenfassung

C60[Cu26Cl26L2{Cp*Fe(η5-P5)}13(CH3CN)9] (L = H2O) represents a first example of a complete encapsulation of C60 itself by an inorganic fullerene-like system via molecular recognition of the five- and sixfold-symmetric structural motif of C60. The product exhibits an inorganic cover consisting of 99 inorganic core atoms from pentaphosphaferrocene and Cu(I) chloride building blocks. This is the first instance of a hollow structure that completely encapsulates C60. The overall spherical molecule possesses an outer diameter of 2.3 nm and shows a remarkable electronic interaction between C60 and the encapsulating giant molecule.

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540 Chemie

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ISO 690SCHEER, Manfred, Andrea SCHINDLER, Roger MERKLE, Brian P. JOHNSON, Michael LINSEIS, Rainer F. WINTER, Christopher E. ANSON, Alexander V. VIROVETS, 2007. Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule. In: Journal of the American Chemical Society. 2007, 129(44), pp. 13386-13387. ISSN 0002-7863. Available under: doi: 10.1021/ja075926m
BibTex
@article{Scheer2007-11-07Fulle-13798,
  year={2007},
  doi={10.1021/ja075926m},
  title={Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule},
  number={44},
  volume={129},
  issn={0002-7863},
  journal={Journal of the American Chemical Society},
  pages={13386--13387},
  author={Scheer, Manfred and Schindler, Andrea and Merkle, Roger and Johnson, Brian P. and Linseis, Michael and Winter, Rainer F. and Anson, Christopher E. and Virovets, Alexander V.}
}
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