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Surface Band Bending Influences the Open-Circuit Voltage of Perovskite Solar Cells

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2019

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ACS Applied Energy Materials. 2019, 2(6), pp. 4045-4052. eISSN 2574-0962. Available under: doi: 10.1021/acsaem.9b00060

Zusammenfassung

With perovskite solar efficiencies exceeding 23%, more investigations are needed to understand and enhance the open-circuit voltage (Voc) for further efficiency gains. Here, by changing the perovskite film annealing conditions, we achieve significant Voc variations in a p–i–n cell architecture. While the morphology remains unaffected, we observe that the annealing conditions affect the surface stoichiometry. Subsequent variations in the Voc are identified to be caused by differences in trap-assisted recombination processes as well as also largely by the suppression of charge collection due to surface band bending. These findings highlight the impact of surface band bending on Voc which can be permanently introduced by normal annealing treatments and impede the charge transport process. Our study suggests that the detailed states of the band bending in perovskite films should be carefully examined and designed to maximize the Voc and consecutively improve the performance of perovskite solar cells.

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530 Physik

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Voc, annealing, band, bending, trap-assisted, recombination, surface

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ISO 690HU, Hao, Susanne T. BIRKHOLD, Muhammad SULTAN, Azhar FAKHARUDDIN, Susanne KOCH, Lukas SCHMIDT-MENDE, 2019. Surface Band Bending Influences the Open-Circuit Voltage of Perovskite Solar Cells. In: ACS Applied Energy Materials. 2019, 2(6), pp. 4045-4052. eISSN 2574-0962. Available under: doi: 10.1021/acsaem.9b00060
BibTex
@article{Hu2019-06-24Surfa-45970,
  year={2019},
  doi={10.1021/acsaem.9b00060},
  title={Surface Band Bending Influences the Open-Circuit Voltage of Perovskite Solar Cells},
  number={6},
  volume={2},
  journal={ACS Applied Energy Materials},
  pages={4045--4052},
  author={Hu, Hao and Birkhold, Susanne T. and Sultan, Muhammad and Fakharuddin, Azhar and Koch, Susanne and Schmidt-Mende, Lukas}
}
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