How to control the scaling of CaCO(3) : a "fingerprinting technique" to classify additives

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Verch Scaling--.pdf
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2011
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Verch, Andreas
Antonietti, Markus
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Physical Chemistry Chemical Physics. 2011, 13(37), pp. 16811-16820. ISSN 1463-9076. eISSN 1463-9084. Available under: doi: 10.1039/c1cp21328h
Zusammenfassung

A titration set-up coupling ion selective electrodes with pH adjustment was used to analyze the effects of additives present during precipitation of calcium carbonate. Besides industrially well-established antiscalants (sodium triphosphate, citrate, polyacrylate and poly(aspartic acid)), also functional polymers being active in morphosynthesis (polystyrene sulfonate and poly(styrene-alt-maleic acid)) were analyzed. Interestingly each additive acts in its specific way, suggesting the notation "fingerprinting" for a complex interplay of up to five "solution modes" of influencing CaCO(3) precipitation and crystallisation. The results provide new insights into the modes of additive controlled crystallisation, and in the long run, the insights may facilitate the design of precipitation systems that yield complex and tailor-made crystals.

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ISO 690VERCH, Andreas, Denis GEBAUER, Markus ANTONIETTI, Helmut CÖLFEN, 2011. How to control the scaling of CaCO(3) : a "fingerprinting technique" to classify additives. In: Physical Chemistry Chemical Physics. 2011, 13(37), pp. 16811-16820. ISSN 1463-9076. eISSN 1463-9084. Available under: doi: 10.1039/c1cp21328h
BibTex
@article{Verch2011-10-06contr-17425,
  year={2011},
  doi={10.1039/c1cp21328h},
  title={How to control the scaling of CaCO(3) : a "fingerprinting technique" to classify additives},
  number={37},
  volume={13},
  issn={1463-9076},
  journal={Physical Chemistry Chemical Physics},
  pages={16811--16820},
  author={Verch, Andreas and Gebauer, Denis and Antonietti, Markus and Cölfen, Helmut}
}
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