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Gram‐scale Total Syntheses of Sarpagine Alkaloids and non‐Natural Derivatives

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2019

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https://doi.org/10.1002/chem.201805644
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European Union (EU): 679418

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ANaPSyS - Artifical Natural Products System Synthesis
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Chemie: Publikationen
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Published

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Chemistry - A European Journal. 2019, 25(11), pp. 2704-2707. ISSN 0947-6539. eISSN 1521-3765. Available under: doi: 10.1002/chem.201805644

Zusammenfassung

This work describes the total synthesis of 3 members of the sarpagine alkaloid family and 10 non‐natural congeners via an improved synthetic sequence which was designed to the point of gram‐scale production of materials suited for SAR‐studies. Furthermore, the manuscript details how the synthetic route was used to access the biogenetically completely unrelated stemona alkaloid parvineostemonine (34), posing a showcase for efficient synthetic design.

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540 Chemie

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ISO 690GAICH, Tanja, Heiko REBMANN, Christa K. G. GERLINGER, 2019. Gram‐scale Total Syntheses of Sarpagine Alkaloids and non‐Natural Derivatives. In: Chemistry - A European Journal. 2019, 25(11), pp. 2704-2707. ISSN 0947-6539. eISSN 1521-3765. Available under: doi: 10.1002/chem.201805644
BibTex
@article{Gaich2019-02-21Grams-44325,
  year={2019},
  doi={10.1002/chem.201805644},
  title={Gram‐scale Total Syntheses of Sarpagine Alkaloids and non‐Natural Derivatives},
  number={11},
  volume={25},
  issn={0947-6539},
  journal={Chemistry - A European Journal},
  pages={2704--2707},
  author={Gaich, Tanja and Rebmann, Heiko and Gerlinger, Christa K. G.}
}
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