Publikation: Adiabatic rotation of effective spin (II) : spin-rotational relaxation
Dateien
Datum
Autor:innen
Herausgeber:innen
ISSN der Zeitschrift
Electronic ISSN
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
URI (zitierfähiger Link)
DOI (zitierfähiger Link)
Internationale Patentnummer
Link zur Lizenz
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Sammlungen
Core Facility der Universität Konstanz
Titel in einer weiteren Sprache
Publikationstyp
Publikationsstatus
Erschienen in
Zusammenfassung
The theory of electron spin-rotational (SR) relaxation in systems with an effective spin S eff = 1/2 is formulated in terms of the adiabaticr otation of effective spin (ARES) approach. It is shown that SR relaxation results from the orientational random walk of the axes of the intramolecular electric field potential (ligand field) to which a spin-bearing atomic center is exposed. The validity of the stochastict reatmentp resented here is not limited by the Redfield conditions. The general expression obtained for the time constant of electrons pin relaxation in liquid phase reproduces the well-known result of Hubbard-Atkins-Kivelson theory if it is specialized to the case of systems with weak spin-orbit coupling.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
Schlagwörter
Konferenz
Rezension
Zitieren
ISO 690
SEREBRENNIKOV, Yuri A., Ulrich STEINER, 1994. Adiabatic rotation of effective spin (II) : spin-rotational relaxation. In: Journal of Chemical Physics. 1994, 100(10), pp. 7508-7514. ISSN 0021-9606. Available under: doi: 10.1063/1.466844BibTex
@article{Serebrennikov1994Adiab-9757, year={1994}, doi={10.1063/1.466844}, title={Adiabatic rotation of effective spin (II) : spin-rotational relaxation}, number={10}, volume={100}, issn={0021-9606}, journal={Journal of Chemical Physics}, pages={7508--7514}, author={Serebrennikov, Yuri A. and Steiner, Ulrich} }
RDF
<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/9757"> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9757"/> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:12Z</dc:date> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/> <dcterms:rights rdf:resource="http://creativecommons.org/licenses/by-nc-nd/2.0/"/> <dc:creator>Serebrennikov, Yuri A.</dc:creator> <dc:format>application/pdf</dc:format> <dcterms:bibliographicCitation>First publ. in: Journal of Chemical Physics 100 (1994), 10, pp. 7508-7514</dcterms:bibliographicCitation> <dc:rights>Attribution-NonCommercial-NoDerivs 2.0 Generic</dc:rights> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9757/1/Adiabatic_rotation_of_effective_spinII.pdf"/> <dcterms:issued>1994</dcterms:issued> <dc:contributor>Serebrennikov, Yuri A.</dc:contributor> <dc:contributor>Steiner, Ulrich</dc:contributor> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9757/1/Adiabatic_rotation_of_effective_spinII.pdf"/> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:12Z</dcterms:available> <foaf:homepage rdf:resource="http://localhost:8080/"/> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dcterms:abstract xml:lang="eng">The theory of electron spin-rotational (SR) relaxation in systems with an effective spin S eff = 1/2 is formulated in terms of the adiabaticr otation of effective spin (ARES) approach. It is shown that SR relaxation results from the orientational random walk of the axes of the intramolecular electric field potential (ligand field) to which a spin-bearing atomic center is exposed. The validity of the stochastict reatmentp resented here is not limited by the Redfield conditions. The general expression obtained for the time constant of electrons pin relaxation in liquid phase reproduces the well-known result of Hubbard-Atkins-Kivelson theory if it is specialized to the case of systems with weak spin-orbit coupling.</dcterms:abstract> <dc:creator>Steiner, Ulrich</dc:creator> <dcterms:title>Adiabatic rotation of effective spin (II) : spin-rotational relaxation</dcterms:title> <dc:language>eng</dc:language> </rdf:Description> </rdf:RDF>