Publikation:

Adiabatic rotation of effective spin (II) : spin-rotational relaxation

Lade...
Vorschaubild

Dateien

Adiabatic_rotation_of_effective_spinII.pdf
Adiabatic_rotation_of_effective_spinII.pdfGröße: 870.94 KBDownloads: 453

Datum

1994

Autor:innen

Serebrennikov, Yuri A.

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

DOI (zitierfähiger Link)
ArXiv-ID

Internationale Patentnummer

Angaben zur Forschungsförderung

Projekt

Open Access-Veröffentlichung
Open Access Green
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

Journal of Chemical Physics. 1994, 100(10), pp. 7508-7514. ISSN 0021-9606. Available under: doi: 10.1063/1.466844

Zusammenfassung

The theory of electron spin-rotational (SR) relaxation in systems with an effective spin S eff = 1/2 is formulated in terms of the adiabaticr otation of effective spin (ARES) approach. It is shown that SR relaxation results from the orientational random walk of the axes of the intramolecular electric field potential (ligand field) to which a spin-bearing atomic center is exposed. The validity of the stochastict reatmentp resented here is not limited by the Redfield conditions. The general expression obtained for the time constant of electrons pin relaxation in liquid phase reproduces the well-known result of Hubbard-Atkins-Kivelson theory if it is specialized to the case of systems with weak spin-orbit coupling.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Zugehörige Datensätze in KOPS

Zitieren

ISO 690SEREBRENNIKOV, Yuri A., Ulrich STEINER, 1994. Adiabatic rotation of effective spin (II) : spin-rotational relaxation. In: Journal of Chemical Physics. 1994, 100(10), pp. 7508-7514. ISSN 0021-9606. Available under: doi: 10.1063/1.466844
BibTex
@article{Serebrennikov1994Adiab-9757,
  year={1994},
  doi={10.1063/1.466844},
  title={Adiabatic rotation of effective spin (II) : spin-rotational relaxation},
  number={10},
  volume={100},
  issn={0021-9606},
  journal={Journal of Chemical Physics},
  pages={7508--7514},
  author={Serebrennikov, Yuri A. and Steiner, Ulrich}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/9757">
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9757"/>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:12Z</dc:date>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:rights rdf:resource="http://creativecommons.org/licenses/by-nc-nd/2.0/"/>
    <dc:creator>Serebrennikov, Yuri A.</dc:creator>
    <dc:format>application/pdf</dc:format>
    <dcterms:bibliographicCitation>First publ. in: Journal of Chemical Physics 100 (1994), 10, pp. 7508-7514</dcterms:bibliographicCitation>
    <dc:rights>Attribution-NonCommercial-NoDerivs 2.0 Generic</dc:rights>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9757/1/Adiabatic_rotation_of_effective_spinII.pdf"/>
    <dcterms:issued>1994</dcterms:issued>
    <dc:contributor>Serebrennikov, Yuri A.</dc:contributor>
    <dc:contributor>Steiner, Ulrich</dc:contributor>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9757/1/Adiabatic_rotation_of_effective_spinII.pdf"/>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:12Z</dcterms:available>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dcterms:abstract xml:lang="eng">The theory of electron spin-rotational (SR) relaxation in systems with an effective spin S eff = 1/2 is formulated in terms of the adiabaticr otation of effective spin (ARES) approach. It is shown that SR relaxation results from the orientational random walk of the axes of the intramolecular electric field potential (ligand field) to which a spin-bearing atomic center is exposed. The validity of the stochastict reatmentp resented here is not limited by the Redfield conditions. The general expression obtained for the time constant of electrons pin relaxation in liquid phase reproduces the well-known result of Hubbard-Atkins-Kivelson theory if it is specialized to the case of systems with weak spin-orbit coupling.</dcterms:abstract>
    <dc:creator>Steiner, Ulrich</dc:creator>
    <dcterms:title>Adiabatic rotation of effective spin (II) : spin-rotational relaxation</dcterms:title>
    <dc:language>eng</dc:language>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Nein
Begutachtet
Diese Publikation teilen