Publikation: Photoelectron spectroscopy of clusters and adsorbates on clusters
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The electronic and geometric structure of free metal cluster anions is studied by photodetachment. The cluster anions are produced in a PACIS (Pulsed Arc Cluster Ion Source). From mass separated bunches of anions electrons are detached by a UV-laser pulse. Photoelectron spectra of the detached electrons are measured with a "magnetic bottle" type time of flight spectrometer. First data on Gan- clusters are presented and compared to similar measurements on Aln- clusters. At the high resolution (~30meV) accessible with this experimental set up comparison of the data with calculations delivers new insights into the geometric structure of the particles. A first application of this technique to molecules adsorbed on metal clusters is presented.
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CHA, Chia-Yen, Gerd GANTEFÖR, Wolfgang EBERHARDT, 1992. Photoelectron spectroscopy of clusters and adsorbates on clusters. In: An international journal of physical chemistry : Berichte der Bunsen-Gesellschaft. 1992, 96(9), pp. 1223-1227. Available under: doi: 10.1002/bbpc.19920960930BibTex
@article{Cha1992Photo-8935, year={1992}, doi={10.1002/bbpc.19920960930}, title={Photoelectron spectroscopy of clusters and adsorbates on clusters}, number={9}, volume={96}, journal={An international journal of physical chemistry : Berichte der Bunsen-Gesellschaft}, pages={1223--1227}, author={Cha, Chia-Yen and Ganteför, Gerd and Eberhardt, Wolfgang} }
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