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Analysis of the conformation of a stiff-chain polyester by measurements of the magnetic birefringence in solution

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1996

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Tiesler, Ulrich
Rehahn, Matthias
Ballauff, Michael
Petekidis, George
Vlassopoulos, Dimitris
Kramer, H.

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http://nbn-resolving.de/urn:nbn:de:bsz:352-176022
DOI (zitierfähiger Link)
https://doi.org/10.1021/ma960765k
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Macromolecules. 1996, 29(21), pp. 6832-6836. ISSN 0024-9297. Available under: doi: 10.1021/ma960765k

Zusammenfassung

The analysis of the conformation of a stiff-chain polyester by magnetic birefringence is presented. The specific Cotton−Mouton constant, C2b, has been measured for five different molecular weights of the polyester. A general analysis of the data is presented, including the effect of polydispersity. A weak dependence of C2b on molecular weight is found, which shows that the persistence length of the polyester is approximately 11 nm. Estimates of the specific Cotton−Mouton constant per unit length by using group increments compare favorably with the measured value.

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530 Physik

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ISO 690TIESLER, Ulrich, Matthias REHAHN, Michael BALLAUFF, George PETEKIDIS, Dimitris VLASSOPOULOS, Georg MARET, H. KRAMER, 1996. Analysis of the conformation of a stiff-chain polyester by measurements of the magnetic birefringence in solution. In: Macromolecules. 1996, 29(21), pp. 6832-6836. ISSN 0024-9297. Available under: doi: 10.1021/ma960765k
BibTex
@article{Tiesler1996Analy-17602,
  year={1996},
  doi={10.1021/ma960765k},
  title={Analysis of the conformation of a stiff-chain polyester by measurements of the magnetic birefringence in solution},
  number={21},
  volume={29},
  issn={0024-9297},
  journal={Macromolecules},
  pages={6832--6836},
  author={Tiesler, Ulrich and Rehahn, Matthias and Ballauff, Michael and Petekidis, George and Vlassopoulos, Dimitris and Maret, Georg and Kramer, H.}
}
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