Publikation:

Bonding of CO to metal particles : photoelectron spectra of Nin(CO)m- and Ptn(CO)m- clusters

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PhysRevLett7619967.pdf
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1996

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Schulze Icking-Konert, Georg
Handschuh, Haiko
Eberhardt, Wolfgang

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http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-87729
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https://doi.org/10.1103/PhysRevLett.76.1047
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Physical Review Letters. 1996, 76(7), pp. 1047-1050. Available under: doi: 10.1103/PhysRevLett.76.1047

Zusammenfassung

Photoelectron spectra of mass-selected negatively charged bare Nin - and Ptn - clusters are compared with the spectra of Nin(CO)m- and Ptn(CO)m - clusters. The spectra indicate that saturation with CO is caused by the formation of an electronic closed shell and not due to steric hindrance as on a surface, and that the strength of the π backdonation of the CO chemisorption bond to a small particle is stronger than to a surface. The antibonding metal (dz2-5σ) orbital resulting from the interaction of the CO 5σ with the metal dz2 orbitals is directly observed for Ni1(CO)3 -.

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ISO 690SCHULZE ICKING-KONERT, Georg, Haiko HANDSCHUH, Gerd GANTEFÖR, Wolfgang EBERHARDT, 1996. Bonding of CO to metal particles : photoelectron spectra of Nin(CO)m- and Ptn(CO)m- clusters. In: Physical Review Letters. 1996, 76(7), pp. 1047-1050. Available under: doi: 10.1103/PhysRevLett.76.1047
BibTex
@article{SchulzeIckingKonert1996Bondi-9310,
  year={1996},
  doi={10.1103/PhysRevLett.76.1047},
  title={Bonding of CO to metal particles : photoelectron spectra of Nin(CO)m- and Ptn(CO)m- clusters},
  number={7},
  volume={76},
  journal={Physical Review Letters},
  pages={1047--1050},
  author={Schulze Icking-Konert, Georg and Handschuh, Haiko and Ganteför, Gerd and Eberhardt, Wolfgang}
}
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