Publikation: Bonding of CO to metal particles : photoelectron spectra of Nin(CO)m- and Ptn(CO)m- clusters
Lade...
Dateien
Datum
1996
Autor:innen
Herausgeber:innen
ISSN der Zeitschrift
Electronic ISSN
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
URI (zitierfähiger Link)
DOI (zitierfähiger Link)
Internationale Patentnummer
Link zur Lizenz
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Open Access Green
Sammlungen
Core Facility der Universität Konstanz
Titel in einer weiteren Sprache
Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published
Erschienen in
Physical Review Letters. 1996, 76(7), pp. 1047-1050. Available under: doi: 10.1103/PhysRevLett.76.1047
Zusammenfassung
Photoelectron spectra of mass-selected negatively charged bare Nin - and Ptn - clusters are compared with the spectra of Nin(CO)m- and Ptn(CO)m - clusters. The spectra indicate that saturation with CO is caused by the formation of an electronic closed shell and not due to steric hindrance as on a surface, and that the strength of the π backdonation of the CO chemisorption bond to a small particle is stronger than to a surface. The antibonding metal (dz2-5σ) orbital resulting from the interaction of the CO 5σ with the metal dz2 orbitals is directly observed for Ni1(CO)3 -.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
530 Physik
Schlagwörter
Konferenz
Rezension
undefined / . - undefined, undefined
Zitieren
ISO 690
SCHULZE ICKING-KONERT, Georg, Haiko HANDSCHUH, Gerd GANTEFÖR, Wolfgang EBERHARDT, 1996. Bonding of CO to metal particles : photoelectron spectra of Nin(CO)m- and Ptn(CO)m- clusters. In: Physical Review Letters. 1996, 76(7), pp. 1047-1050. Available under: doi: 10.1103/PhysRevLett.76.1047BibTex
@article{SchulzeIckingKonert1996Bondi-9310, year={1996}, doi={10.1103/PhysRevLett.76.1047}, title={Bonding of CO to metal particles : photoelectron spectra of Nin(CO)m- and Ptn(CO)m- clusters}, number={7}, volume={76}, journal={Physical Review Letters}, pages={1047--1050}, author={Schulze Icking-Konert, Georg and Handschuh, Haiko and Ganteför, Gerd and Eberhardt, Wolfgang} }
RDF
<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/9310"> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:rights>terms-of-use</dc:rights> <dcterms:issued>1996</dcterms:issued> <dc:creator>Eberhardt, Wolfgang</dc:creator> <dc:creator>Ganteför, Gerd</dc:creator> <dc:creator>Handschuh, Haiko</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9310"/> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T17:55:23Z</dcterms:available> <dcterms:bibliographicCitation>First publ. in: Physical Review Letters 76 (1996), 7, pp. 1047-1050</dcterms:bibliographicCitation> <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9310/1/PhysRevLett7619967.pdf"/> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/> <dc:contributor>Ganteför, Gerd</dc:contributor> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/> <dc:contributor>Eberhardt, Wolfgang</dc:contributor> <dc:format>application/pdf</dc:format> <dc:creator>Schulze Icking-Konert, Georg</dc:creator> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9310/1/PhysRevLett7619967.pdf"/> <dc:contributor>Handschuh, Haiko</dc:contributor> <dcterms:title>Bonding of CO to metal particles : photoelectron spectra of Nin(CO)m- and Ptn(CO)m- clusters</dcterms:title> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T17:55:23Z</dc:date> <foaf:homepage rdf:resource="http://localhost:8080/"/> <dc:contributor>Schulze Icking-Konert, Georg</dc:contributor> <dc:language>eng</dc:language> <dcterms:abstract xml:lang="eng">Photoelectron spectra of mass-selected negatively charged bare Nin - and Ptn - clusters are compared with the spectra of Nin(CO)m- and Ptn(CO)m - clusters. The spectra indicate that saturation with CO is caused by the formation of an electronic closed shell and not due to steric hindrance as on a surface, and that the strength of the π backdonation of the CO chemisorption bond to a small particle is stronger than to a surface. The antibonding metal (dz2-5σ) orbital resulting from the interaction of the CO 5σ with the metal dz2 orbitals is directly observed for Ni1(CO)3 -.</dcterms:abstract> </rdf:Description> </rdf:RDF>
Interner Vermerk
xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter
Prüfungsdatum der Dissertation
Finanzierungsart
Kommentar zur Publikation
Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Nein