Fabrication of EuF3-Mesocrystals in a Gel Matrix
| dc.contributor.author | Lausser, Christine | deu |
| dc.contributor.author | Kumke, Michael U. | deu |
| dc.contributor.author | Antonietti, Markus | deu |
| dc.contributor.author | Cölfen, Helmut | |
| dc.date.accessioned | 2011-03-24T18:14:41Z | deu |
| dc.date.available | 2011-03-24T18:14:41Z | deu |
| dc.date.issued | 2010 | deu |
| dc.description.abstract | Europium(III) fluoride mesocrystals were synthesised in an organic matrix. This matrix is a gel formed by Eu3+ ions and a polycarboxylate/sulfonate copolymer, ACUSOL 588G. In the gel phase, the local amount of europium ions is very high since Eu3+ acts as a crosslinker, and crystallisation occurs upon addition of F . Nucleated seed crystals in the gel phase grow by further ion attachment and form mesocrystals by mutual orientation of the EuF3 particles in the gel. We propose a dipole field as reason for this alignment and that the dipolar character of the particles originates from adsorption of the polyelectrolyte on charged crystal faces. | eng |
| dc.description.version | published | |
| dc.format.mimetype | application/pdf | deu |
| dc.identifier.citation | First publ. in: Zeitschrift für anorganische und allgemeine Chemie 636 (2010), 11, pp. 1925-1930 | deu |
| dc.identifier.doi | 10.1002/zaac.201000098 | |
| dc.identifier.ppn | 336224052 | deu |
| dc.identifier.uri | http://kops.uni-konstanz.de/handle/123456789/9826 | |
| dc.language.iso | eng | deu |
| dc.legacy.dateIssued | 2011 | deu |
| dc.rights | terms-of-use | deu |
| dc.rights.uri | https://rightsstatements.org/page/InC/1.0/ | deu |
| dc.subject | Mesocrystals | deu |
| dc.subject | Non-classical crystallisation | deu |
| dc.subject | Europium | deu |
| dc.subject | Fluorine | deu |
| dc.subject | Crystal growth | deu |
| dc.subject.ddc | 540 | deu |
| dc.title | Fabrication of EuF3-Mesocrystals in a Gel Matrix | eng |
| dc.type | JOURNAL_ARTICLE | deu |
| dspace.entity.type | Publication | |
| kops.citation.bibtex | @article{Lausser2010Fabri-9826,
year={2010},
doi={10.1002/zaac.201000098},
title={Fabrication of EuF3-Mesocrystals in a Gel Matrix},
number={11},
volume={636},
journal={Zeitschrift für anorganische und allgemeine Chemie},
pages={1925--1930},
author={Lausser, Christine and Kumke, Michael U. and Antonietti, Markus and Cölfen, Helmut}
} | |
| kops.citation.iso690 | LAUSSER, Christine, Michael U. KUMKE, Markus ANTONIETTI, Helmut CÖLFEN, 2010. Fabrication of EuF3-Mesocrystals in a Gel Matrix. In: Zeitschrift für anorganische und allgemeine Chemie. 2010, 636(11), pp. 1925-1930. eISSN 0044-2313. Available under: doi: 10.1002/zaac.201000098 | deu |
| kops.citation.iso690 | LAUSSER, Christine, Michael U. KUMKE, Markus ANTONIETTI, Helmut CÖLFEN, 2010. Fabrication of EuF3-Mesocrystals in a Gel Matrix. In: Zeitschrift für anorganische und allgemeine Chemie. 2010, 636(11), pp. 1925-1930. eISSN 0044-2313. Available under: doi: 10.1002/zaac.201000098 | eng |
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<dcterms:abstract xml:lang="eng">Europium(III) fluoride mesocrystals were synthesised in an organic matrix. This matrix is a gel formed by Eu3+ ions and a polycarboxylate/sulfonate copolymer, ACUSOL 588G. In the gel phase, the local amount of europium ions is very high since Eu3+ acts as a crosslinker, and crystallisation occurs upon addition of F . Nucleated seed crystals in the gel phase grow by further ion attachment and form mesocrystals by mutual orientation of the EuF3 particles in the gel. We propose a dipole field as reason for this alignment and that the dipolar character of the particles originates from adsorption of the polyelectrolyte on charged crystal faces.</dcterms:abstract>
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| source.bibliographicInfo.fromPage | 1925 | |
| source.bibliographicInfo.issue | 11 | |
| source.bibliographicInfo.toPage | 1930 | |
| source.bibliographicInfo.volume | 636 | |
| source.identifier.eissn | 0044-2313 | |
| source.periodicalTitle | Zeitschrift für anorganische und allgemeine Chemie |
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