Publikation:

Tetraruthenium Macrocycles with Laterally Extended Bis(alkenyl)quinoxaline Ligands and Their F4TCNQ•− Salts

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Das_2-scqv61bb2h2m7.pdf
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Datum

2022

Autor:innen

Senft, Laura
Ivanović-Burmazović, Ivana

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http://nbn-resolving.de/urn:nbn:de:bsz:352-2-scqv61bb2h2m7
DOI (zitierfähiger Link)
https://doi.org/10.3390/inorganics10060082
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CC BY 4.0

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Open Access Gold

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Chemie: Publikationen
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Published

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Inorganics. MDPI. 2022, 10(6), 82. eISSN 2304-6740. Available under: doi: 10.3390/inorganics10060082

Zusammenfassung

We report on the tetraruthenium macrocycles Ru4-5 and -6 with a π-conjugated pyrene-appended 5,8-divinylquinoxaline ligand and either isophthalate or thiophenyl-2,5-dicarboxylate linkers and their charge-transfer salts formed by oxidation with two equivalents of F4TCNQ. Both macrocyclic complexes were characterized by NMR spectroscopy, mass spectrometry, cyclic and square-wave voltammetry, and by IR, UV–vis–NIR, and EPR spectroscopy in their various oxidation states.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

metallamacrocycle; ruthenium; electrochemistry; spectroelectrochemistry; X-ray crystallography; charge-transfer salts

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ISO 690DAS, Rajorshi, Michael LINSEIS, Laura SENFT, Ivana IVANOVIĆ-BURMAZOVIĆ, Rainer F. WINTER, 2022. Tetraruthenium Macrocycles with Laterally Extended Bis(alkenyl)quinoxaline Ligands and Their F4TCNQ•− Salts. In: Inorganics. MDPI. 2022, 10(6), 82. eISSN 2304-6740. Available under: doi: 10.3390/inorganics10060082
BibTex
@article{Das2022-06-14Tetra-57953,
  year={2022},
  doi={10.3390/inorganics10060082},
  title={Tetraruthenium Macrocycles with Laterally Extended Bis(alkenyl)quinoxaline Ligands and Their F<sub>4</sub>TCNQ<sup>•−</sup> Salts},
  number={6},
  volume={10},
  journal={Inorganics},
  author={Das, Rajorshi and Linseis, Michael and Senft, Laura and Ivanović-Burmazović, Ivana and Winter, Rainer F.},
  note={Article Number: 82}
}
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    <dcterms:abstract xml:lang="eng">We report on the tetraruthenium macrocycles Ru&lt;sub&gt;4&lt;/sub&gt;-5 and -6 with a π-conjugated pyrene-appended 5,8-divinylquinoxaline ligand and either isophthalate or thiophenyl-2,5-dicarboxylate linkers and their charge-transfer salts formed by oxidation with two equivalents of F&lt;sub&gt;4&lt;/sub&gt;TCNQ. Both macrocyclic complexes were characterized by NMR spectroscopy, mass spectrometry, cyclic and square-wave voltammetry, and by IR, UV–vis–NIR, and EPR spectroscopy in their various oxidation states.</dcterms:abstract>
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