Publikation: Mechanistic Studies of Catalytic Polyethylene Chain Growth in the Presence of Water
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Datum
2006
Autor:innen
Berkefeld, Andreas
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Core Facility der Universität Konstanz
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Angewandte Chemie International Edition. 2006, 45(36), pp. 6044-6046. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.200601387
Zusammenfassung
Position blocked? Quantitative studies of polyethylene chain growth in the presence of water by variable‐temperature (VT) 1H NMR spectroscopy show, unexpectedly, that water can compete with monomer binding at the vacant coordination site in cationic diimine palladium(II) methyl as well as higher alkyl complexes (see scheme); the latter are prepared cleanly as water complexes at T<0 °C.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
540 Chemie
Schlagwörter
chain growth, homogeneous catalysis, palladium, polymerization, Water
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BERKEFELD, Andreas, Stefan MECKING, 2006. Mechanistic Studies of Catalytic Polyethylene Chain Growth in the Presence of Water. In: Angewandte Chemie International Edition. 2006, 45(36), pp. 6044-6046. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.200601387BibTex
@article{Berkefeld2006-09-11Mecha-42186, year={2006}, doi={10.1002/anie.200601387}, title={Mechanistic Studies of Catalytic Polyethylene Chain Growth in the Presence of Water}, number={36}, volume={45}, issn={1433-7851}, journal={Angewandte Chemie International Edition}, pages={6044--6046}, author={Berkefeld, Andreas and Mecking, Stefan} }
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