Publikation: An empirical constitutive law for concentrated colloidal suspensions in the approach of the glass transition
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2009
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Rheologica acta. 2009, 48(7), pp. 747-753. Available under: doi: 10.1007/s00397-009-0377-5
Zusammenfassung
Concentrated, non-crystallizing colloidal suspensions in their approach of the glass state exhibit distinct dynamics patterns. These patterns suggest a powerlaw rheological constitutive model for nearglass viscoelasticity, as presented here. The rheological parameters used for this model originate in the mode-coupling theory. The proposed constitutive model provides explicit expressions for the steady shear viscosity, the steady normal stress coefficient, the modulus-compliance relation, and the α peak of G''. The relaxation pattern distinctly differs from gelation
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
530 Physik
Schlagwörter
Glass transition, Mode-coupling theory, Colloidal glass, BSW spectrum, Linear viscoelasticity, Near-glass dynamics
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WINTER, Henning, Miriam SIEBENBÜRGER, David HAJNAL, Oliver HENRICH, Matthias FUCHS, Matthias BALLAUFF, 2009. An empirical constitutive law for concentrated colloidal suspensions in the approach of the glass transition. In: Rheologica acta. 2009, 48(7), pp. 747-753. Available under: doi: 10.1007/s00397-009-0377-5BibTex
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year={2009},
doi={10.1007/s00397-009-0377-5},
title={An empirical constitutive law for concentrated colloidal suspensions in the approach of the glass transition},
number={7},
volume={48},
journal={Rheologica acta},
pages={747--753},
author={Winter, Henning and Siebenbürger, Miriam and Hajnal, David and Henrich, Oliver and Fuchs, Matthias and Ballauff, Matthias}
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