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Multimetallic Gold-Iron Compounds Based on Aurated Ferrocenes

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2017

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Meyer, Nadine
Schucht, Heike
Lehmann, Christian W.
Mohr, Fabian

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https://doi.org/10.1002/ejic.201601458
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European Journal of Inorganic Chemistry. 2017, 2017(2), pp. 521-526. ISSN 1434-1948. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201601458

Zusammenfassung

A family of aurated ferrocenes was prepared by a transmetallation reaction using ferroceneboronic acid derivatives. With this method, multimetallic ferrocenyl complexes [FcAu(PPh3)] {Fc = (η5-C5H4)FeCp} and [(µ-P-P)(AuFc)2] {P-P = dppe, dppf}, as well as 1,1′-diaurated ferrocenes [Fe(η5-C5H4AuPPh3)2] and [Fe{(η5-C5H4Au)}2(µ-P-P)] {P-P = dppe, dppf}, were obtained in high yields as air-stable orange materials. The compounds were characterised by spectroscopic methods, cyclic voltammetry and single-crystal X-ray diffraction. The reactivity of the dinuclear gold(I) complex in oxidative addition reactions is also reported.

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ISO 690MEYER, Nadine, Heike SCHUCHT, Christian W. LEHMANN, Bernhard WEIBERT, Rainer F. WINTER, Fabian MOHR, 2017. Multimetallic Gold-Iron Compounds Based on Aurated Ferrocenes. In: European Journal of Inorganic Chemistry. 2017, 2017(2), pp. 521-526. ISSN 1434-1948. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201601458
BibTex
@article{Meyer2017Multi-36870,
  year={2017},
  doi={10.1002/ejic.201601458},
  title={Multimetallic Gold-Iron Compounds Based on Aurated Ferrocenes},
  number={2},
  volume={2017},
  issn={1434-1948},
  journal={European Journal of Inorganic Chemistry},
  pages={521--526},
  author={Meyer, Nadine and Schucht, Heike and Lehmann, Christian W. and Weibert, Bernhard and Winter, Rainer F. and Mohr, Fabian}
}
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