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Second-harmonic generation effect enhanced by Li substitution for Na in Li1(LiXNa5−X)Mo9O30

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2024

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Vuksan, Victor Z.
Cheng, Y.
Park, Sohyun
Gméling, Katalin
Szentmiklósi, László

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Journal of Solid State Chemistry. Elsevier. 2024, 339, 124920. ISSN 0022-4596. eISSN 1095-726X. Verfügbar unter: doi: 10.1016/j.jssc.2024.124920

Zusammenfassung

Large single crystals of the solid-solution series Li1(LiXNa5–X)Mo9O30 were grown by the Czochralski method by varying the Li substitution for Na. Structure analyses with X-ray single-crystal diffraction data elucidated statistic disorder of Li with Na at three independent Na sites. The resulting Li substitution X = 0, 1.2, and 2.8 could be confirmed by neutron activation analysis. Second-harmonic generation (SHG) light intensities and non-linear optical (NLO) coefficients were determined in three crystallographic main directions by Maker fringe measurements. DFT calculations delivered absolute NLO magnitudes. UV/Vis optical spectra revealed that the transmission rises from X = 0 to X = 2.8. However, the SHG effect is at largest in Li1(Li1.2Na3.8)Mo9O30 (X = 1.2), so far investigated in this study.

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540 Chemie

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Second-harmonicgeneration, Li-Na-molybdates, Structure-relatedopticalproperties

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ISO 690VUKSAN, Victor Z., Y. CHENG, Sohyun PARK, Elena V. STURM, Katalin GMÉLING, László SZENTMIKLÓSI, 2024. Second-harmonic generation effect enhanced by Li substitution for Na in Li1(LiXNa5−X)Mo9O30. In: Journal of Solid State Chemistry. Elsevier. 2024, 339, 124920. ISSN 0022-4596. eISSN 1095-726X. Verfügbar unter: doi: 10.1016/j.jssc.2024.124920
BibTex
@article{Vuksan2024-11Secon-70782,
  year={2024},
  doi={10.1016/j.jssc.2024.124920},
  title={Second-harmonic generation effect enhanced by Li substitution for Na in Li<sub>1</sub>(Li<sub>X</sub>Na<sub>5−X</sub>)Mo<sub>9</sub>O<sub>30</sub>},
  volume={339},
  issn={0022-4596},
  journal={Journal of Solid State Chemistry},
  author={Vuksan, Victor Z. and Cheng, Y. and Park, Sohyun and Sturm, Elena V. and Gméling, Katalin and Szentmiklósi, László},
  note={Article Number: 124920}
}
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