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Compartmentalized polymerization in aqueous and organic media to low-entangled ultra high molecular weight polyethylene

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2021

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Polymer Chemistry. Royal Society of Chemistry (RSC). 2021, 12(21), pp. 3116-3123. ISSN 1759-9954. eISSN 1759-9962. Available under: doi: 10.1039/D1PY00394A

Zusammenfassung

Catalytic copolymerization with functional group tolerant lipophilic Ni(II) catalysts in aqueous emulsion-type polymerization or dispersion polymerization in organic solvents (THF, n-heptane) yields ultra high molecular weight polyethylene (UHMWPE) as submicron- or micron-sized, respectively, particles. Precise multiblock copolymers with crystallizable C46 polyethylene blocks and amorphous soluble polybutene blocks, as well as a random ethylene-octene copolymer with similar block lengths were suitable for particle stabilization in the organic dispersion polymerizations.

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ISO 690WIMMER, Florian P., Viktoria EBEL, Felix SCHMIDT, Stefan MECKING, 2021. Compartmentalized polymerization in aqueous and organic media to low-entangled ultra high molecular weight polyethylene. In: Polymer Chemistry. Royal Society of Chemistry (RSC). 2021, 12(21), pp. 3116-3123. ISSN 1759-9954. eISSN 1759-9962. Available under: doi: 10.1039/D1PY00394A
BibTex
@article{Wimmer2021Compa-53749,
  year={2021},
  doi={10.1039/D1PY00394A},
  title={Compartmentalized polymerization in aqueous and organic media to low-entangled ultra high molecular weight polyethylene},
  number={21},
  volume={12},
  issn={1759-9954},
  journal={Polymer Chemistry},
  pages={3116--3123},
  author={Wimmer, Florian P. and Ebel, Viktoria and Schmidt, Felix and Mecking, Stefan}
}
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