Publikation: Compartmentalized polymerization in aqueous and organic media to low-entangled ultra high molecular weight polyethylene
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2021
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Polymer Chemistry. Royal Society of Chemistry (RSC). 2021, 12(21), pp. 3116-3123. ISSN 1759-9954. eISSN 1759-9962. Available under: doi: 10.1039/D1PY00394A
Zusammenfassung
Catalytic copolymerization with functional group tolerant lipophilic Ni(II) catalysts in aqueous emulsion-type polymerization or dispersion polymerization in organic solvents (THF, n-heptane) yields ultra high molecular weight polyethylene (UHMWPE) as submicron- or micron-sized, respectively, particles. Precise multiblock copolymers with crystallizable C46 polyethylene blocks and amorphous soluble polybutene blocks, as well as a random ethylene-octene copolymer with similar block lengths were suitable for particle stabilization in the organic dispersion polymerizations.
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540 Chemie
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WIMMER, Florian P., Viktoria EBEL, Felix SCHMIDT, Stefan MECKING, 2021. Compartmentalized polymerization in aqueous and organic media to low-entangled ultra high molecular weight polyethylene. In: Polymer Chemistry. Royal Society of Chemistry (RSC). 2021, 12(21), pp. 3116-3123. ISSN 1759-9954. eISSN 1759-9962. Available under: doi: 10.1039/D1PY00394ABibTex
@article{Wimmer2021Compa-53749, year={2021}, doi={10.1039/D1PY00394A}, title={Compartmentalized polymerization in aqueous and organic media to low-entangled ultra high molecular weight polyethylene}, number={21}, volume={12}, issn={1759-9954}, journal={Polymer Chemistry}, pages={3116--3123}, author={Wimmer, Florian P. and Ebel, Viktoria and Schmidt, Felix and Mecking, Stefan} }
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