Publikation:

Dimedone : A Versatile Precursor for Annulated Heterocycles

Lade...
Vorschaubild

Dateien

Zu diesem Dokument gibt es keine Dateien.

Datum

2009

Autor:innen

Awad, Laila F.
El Kilany, Yeldez
Ibrahim, Elsayed I.

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

URI (zitierfähiger Link)
ArXiv-ID

Internationale Patentnummer

Angaben zur Forschungsförderung

Projekt

Open Access-Veröffentlichung
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

Advances in Heterocyclic Chemistry. Elsevier. 2009, 98, pp. 1-141. ISSN 0065-2725. eISSN 1557-8429. Available under: doi: 10.1016/S0065-2725(09)09801-8

Zusammenfassung

This chapter explores that dimedone is a versatile precursor for annulated heterocycles. Dimedone(1) is an alicyclic compound having 1,3-dicarbonyl groups flanked by a methylene group and exists in a tautomeric transenolized form where intramolecular hydrogen bonding is not possible. Dimedone is an excellent precursor for partially hydrogenated fused heterocycles where two of the carbon atoms of dimedone are part of the backbone of the formed heterocycles. The chapter illustrates that dimedone's structural features and its reactivity to form more functionalized derivatives have led to the construction of a wide range of fused or spiral biheterocycles. Finally, this chapter emphasizes the role of 1 in the synthesis of fused heterocycles, classified according to the size of the ring and the number of heteroatoms in the heterocycle fused to the cyclohexane ring and subdivided according to the heteroatoms and their arrangement in the ring.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Zugehörige Datensätze in KOPS

Zitieren

ISO 690EL ASHRY, El Sayed H., Laila F. AWAD, Yeldez EL KILANY, Elsayed I. IBRAHIM, 2009. Dimedone : A Versatile Precursor for Annulated Heterocycles. In: Advances in Heterocyclic Chemistry. Elsevier. 2009, 98, pp. 1-141. ISSN 0065-2725. eISSN 1557-8429. Available under: doi: 10.1016/S0065-2725(09)09801-8
BibTex
@article{ElAshry2009Dimed-58056,
  year={2009},
  doi={10.1016/S0065-2725(09)09801-8},
  title={Dimedone : A Versatile Precursor for Annulated Heterocycles},
  volume={98},
  issn={0065-2725},
  journal={Advances in Heterocyclic Chemistry},
  pages={1--141},
  author={El Ashry, El Sayed H. and Awad, Laila F. and El Kilany, Yeldez and Ibrahim, Elsayed I.}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/58056">
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:contributor>El Kilany, Yeldez</dc:contributor>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2022-07-15T07:56:18Z</dcterms:available>
    <dc:language>eng</dc:language>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dcterms:issued>2009</dcterms:issued>
    <dc:creator>El Ashry, El Sayed H.</dc:creator>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:title>Dimedone : A Versatile Precursor for Annulated Heterocycles</dcterms:title>
    <dc:contributor>Ibrahim, Elsayed I.</dc:contributor>
    <dc:creator>El Kilany, Yeldez</dc:creator>
    <dcterms:abstract xml:lang="eng">This chapter explores that dimedone is a versatile precursor for annulated heterocycles. Dimedone(1) is an alicyclic compound having 1,3-dicarbonyl groups flanked by a methylene group and exists in a tautomeric transenolized form where intramolecular hydrogen bonding is not possible. Dimedone is an excellent precursor for partially hydrogenated fused heterocycles where two of the carbon atoms of dimedone are part of the backbone of the formed heterocycles. The chapter illustrates that dimedone's structural features and its reactivity to form more functionalized derivatives have led to the construction of a wide range of fused or spiral biheterocycles. Finally, this chapter emphasizes the role of 1 in the synthesis of fused heterocycles, classified according to the size of the ring and the number of heteroatoms in the heterocycle fused to the cyclohexane ring and subdivided according to the heteroatoms and their arrangement in the ring.</dcterms:abstract>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2022-07-15T07:56:18Z</dc:date>
    <dc:contributor>Awad, Laila F.</dc:contributor>
    <dc:creator>Awad, Laila F.</dc:creator>
    <dc:contributor>El Ashry, El Sayed H.</dc:contributor>
    <dc:creator>Ibrahim, Elsayed I.</dc:creator>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/58056"/>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Begutachtet
Unbekannt
Diese Publikation teilen