Publikation:

The reaction of aluminum cluster anions with tetrakis(dimethylamino)ethylene (TDMAE) : Insertion of an aluminum anion into a C–N bond

Vorschaubild

Dateien

Zu diesem Dokument gibt es keine Dateien.

Datum

2009

Autor:innen

Li, Xiang
Grubisic, Andrej
Eustis, Soren
Wang, Di
Lectka, Thomas
Bowen, Kit H.
Burgert, Ralf
Schnöckel, Hansgeorg

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

URI (zitierfähiger Link)
DOI (zitierfähiger Link)
https://doi.org/10.1016/j.cplett.2009.09.101
ArXiv-ID

Internationale Patentnummer

Angaben zur Forschungsförderung

Projekt

Open Access-Veröffentlichung

Sammlungen

Physik: Publikationen
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

Chemical Physics Letters. Elsevier. 2009, 481(4-6), pp. 190-193. ISSN 0009-2614. eISSN 1873-4448. Available under: doi: 10.1016/j.cplett.2009.09.101

Zusammenfassung

The reactivity of aluminum cluster anions with tetrakis(dimethylamino)ethylene (TDMAE) has been studied using mass spectrometry. All aluminum cluster anions, regardless of their size, disappeared from the mass spectrum upon introduction of TDMAE, leaving behind the single anionic reaction product, [Al(TDMAE)]−. The combination of anionic photoelectron spectroscopy and density functional theory was then employed to probe the structure of this anion. Contrary to the π-complex structure known in Al-alkene systems, [Al(TDMAE)]− was found to prefer a 2 eV more stable geometry in which Al− inserted into one of the C–N bonds in TDMAE.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
530 Physik

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Zugehörige Datensätze in KOPS

Zitieren

ISO 690LI, Xiang, Andrej GRUBISIC, Soren EUSTIS, Di WANG, Thomas LECTKA, Gerd GANTEFÖR, Kit H. BOWEN, Ralf BURGERT, Hansgeorg SCHNÖCKEL, 2009. The reaction of aluminum cluster anions with tetrakis(dimethylamino)ethylene (TDMAE) : Insertion of an aluminum anion into a C–N bond. In: Chemical Physics Letters. Elsevier. 2009, 481(4-6), pp. 190-193. ISSN 0009-2614. eISSN 1873-4448. Available under: doi: 10.1016/j.cplett.2009.09.101
BibTex
@article{Li2009react-58512,
  year={2009},
  doi={10.1016/j.cplett.2009.09.101},
  title={The reaction of aluminum cluster anions with tetrakis(dimethylamino)ethylene (TDMAE) : Insertion of an aluminum anion into a C–N bond},
  number={4-6},
  volume={481},
  issn={0009-2614},
  journal={Chemical Physics Letters},
  pages={190--193},
  author={Li, Xiang and Grubisic, Andrej and Eustis, Soren and Wang, Di and Lectka, Thomas and Ganteför, Gerd and Bowen, Kit H. and Burgert, Ralf and Schnöckel, Hansgeorg}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/58512">
    <dc:creator>Burgert, Ralf</dc:creator>
    <dc:contributor>Burgert, Ralf</dc:contributor>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dc:creator>Schnöckel, Hansgeorg</dc:creator>
    <dc:contributor>Wang, Di</dc:contributor>
    <dc:creator>Lectka, Thomas</dc:creator>
    <dc:contributor>Schnöckel, Hansgeorg</dc:contributor>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2022-09-06T13:59:52Z</dcterms:available>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dcterms:title>The reaction of aluminum cluster anions with tetrakis(dimethylamino)ethylene (TDMAE) : Insertion of an aluminum anion into a C–N bond</dcterms:title>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2022-09-06T13:59:52Z</dc:date>
    <dc:creator>Li, Xiang</dc:creator>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:creator>Grubisic, Andrej</dc:creator>
    <dcterms:abstract xml:lang="eng">The reactivity of aluminum cluster anions with tetrakis(dimethylamino)ethylene (TDMAE) has been studied using mass spectrometry. All aluminum cluster anions, regardless of their size, disappeared from the mass spectrum upon introduction of TDMAE, leaving behind the single anionic reaction product, [Al(TDMAE)]−. The combination of anionic photoelectron spectroscopy and density functional theory was then employed to probe the structure of this anion. Contrary to the π-complex structure known in Al-alkene systems, [Al(TDMAE)]− was found to prefer a 2 eV more stable geometry in which Al− inserted into one of the C–N bonds in TDMAE.</dcterms:abstract>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dc:creator>Ganteför, Gerd</dc:creator>
    <dc:contributor>Bowen, Kit H.</dc:contributor>
    <dc:contributor>Eustis, Soren</dc:contributor>
    <dc:creator>Bowen, Kit H.</dc:creator>
    <dcterms:issued>2009</dcterms:issued>
    <dc:contributor>Grubisic, Andrej</dc:contributor>
    <dc:contributor>Li, Xiang</dc:contributor>
    <dc:creator>Wang, Di</dc:creator>
    <dc:language>eng</dc:language>
    <dc:contributor>Lectka, Thomas</dc:contributor>
    <dc:contributor>Ganteför, Gerd</dc:contributor>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/58512"/>
    <dc:creator>Eustis, Soren</dc:creator>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
Begutachtet
Ja
Diese Publikation teilen